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When diethyl succinate (1) is treated with NaOEt in EtOH, the major product is diethyl 2,5-dioxocyclohexane-1,4-dicarboxylate (2) after a mild acidic workup. Select the best detailed, step-wise, arrow-pushing mechanism for the formation of 2 from 1. 1.) NaOEt, E1OH EtO 2.) H3O+ OEt EtO. EtO. (2 equiv) 1 O.. : OEt a.) :0: OEt EtO EtO EtO EtO H. EtO. EtO. EtO EtO, OEt EtO EtO EtO EtO. EtO. EtO, LOEt OEt O :0: -ö:

When diethyl succinate (1) is treated with NaOEt in EtOH, the major product is diethyl 2,5-dioxocyclohexane-1,4-dicarboxylate (2) after a mild acidic workup. Select the best detailed, step-wise, arrow-pushing mechanism for the formation of 2 from 1. 1.) NaOEt, E1OH EtO 2.) H3O+ OEt EtO. EtO. (2 equiv) 1 O.. : OEt a.) :0: OEt EtO EtO EtO EtO H. EtO. EtO. EtO EtO, OEt EtO EtO EtO EtO. EtO. EtO, LOEt OEt O :0: -ö:

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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When diethyl succinate (1) is treated with NaOEt in EtOH, the major product is diethyl 2,5-dioxocyclohexane-1,4-dicarboxylate (2) after a mild acidic workup. Select the best detailed, step-wise, arrow-pushing mechanism for the formation of 2 from 1. 1.) NaOEt, E1OH EtO 2.) H30+ OEt EtO. EtO. (2 equiv) 1 O.. : OEt a.) :0: OEt EtO EtO EtO EtO H. EtO. EtO. EtO EtO, OEt EtO EtO EtO EtO. EtO. EtO, COEt OEt O :0: -ö:
Transcribed Image Text:When diethyl succinate (1) is treated with NaOEt in EtOH, the major product is diethyl 2,5-dioxocyclohexane-1,4-dicarboxylate (2) after a mild acidic workup. Select the best detailed, step-wise, arrow-pushing mechanism for the formation of 2 from 1. 1.) NaOEt, E1OH EtO 2.) H30+ OEt EtO. EtO. (2 equiv) 1 O.. : OEt a.) :0: OEt EtO EtO EtO EtO H. EtO. EtO. EtO EtO, OEt EtO EtO EtO EtO. EtO. EtO, COEt OEt O :0: -ö:
b.) OEL OEt EtO EtO EtO EtO H. Et EtO, EtO. EtO. EtO. OEt EtO EtO EtO OEt EtO. OEt EtO. OEt EtO : OEt c.) OEt : OEt EtO EtO EtO EtO EtO EtO EtO EtO. OEt C OEt 1. O= O ö: 0= O 1
Transcribed Image Text:b.) OEL OEt EtO EtO EtO EtO H. Et EtO, EtO. EtO. EtO. OEt EtO EtO EtO OEt EtO. OEt EtO. OEt EtO : OEt c.) OEt : OEt EtO EtO EtO EtO EtO EtO EtO EtO. OEt C OEt 1. O= O ö: 0= O 1
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