When a vacuum is created on a certain amount of water contained in a rigid, airtight container, certain effects are observed. Indicate which of them does not occur:(A). The temperature of the water decreases(B). The vapor pressure of the water decreases(C). The mass of liquid water decreases(D). The water decomposes into H2 and O2, gases that remain in equilibrium with the liquid phase

5-106 The normal boiling point of hexane, C6H14, is 69°C, and that of pentane, C5H12, is 36°C. Predict which of these compounds has a higher vapor pressure at 20°C.

Butane is a gas at room temperature; however, if you look closely at a butane lighter you see it contains liquid butane. Explain how it is possible to have liquid butane present.

Chloroform, CHCl3, has a normal boiling point of 61C. Its vapor pressure at 43C is 0.526 atm. What is the concentration (in g/L) of CHCl3 when it saturates the air at 27C?

Define the normal boiling point of water. Why does a sample of boiling water remain at the same temperature until all the water has been boiled? Define the normal freezing point of water. Sketch a representation of a heating/cooling curve for water, marking clearly the normal freezing and boiling points.

Consider the following data for the vapor pressure of diethyl ether, a widely used anesthetic in the early days of surgery. Follow the instructions in Question 13 to estimate the heat of vaporization of diethyl ether.

8.52 Rank the following hydrocarbons in order of increasing vapor pressure: C2H6,C10H22,CH4,C7H16,C22H46 .

A solution of benzoic acid in benzene has a freezing point of 3.1 C and a boiling point of 82.6 C. (The freezing point of pure benzene is 5.50 C, and its boiling point is 80.1 C) The structure of benzoic acid is Benzoic acid, C6H5CO2H What can you conclude about the state of the benzoic acid molecules at the two different temperatures? Recall the discussion of hydrogen bonding in Section 11.3.

How many grams of water at 0C will be melted by the condensation of 1 g of steam at 100C?

3. (a) The Lattice enthalpy for the solid ionic compound AgBr is +900. kJ/mole. Write the chemical equation that corresponds to the Lattice Enthalpy for AgBr(s) in the space above. Then explain in your own words why this is a large positive number. (b) The hydration enthalpy for AgBris -821 kJ/mole. Write the chemical equation that corresponds to the Hydration Enthalpy for AgBr(s) in the space above. Then explain in your own words why this is a large negative number. (c) Would you expect this compound to be soluble in water? Why/Why not? Calculate anything you need in order to figure this out, and explain your answer.