Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
Related questions
Question
When a 2.45-g sample of solid sodium hydroxide dissolves in 41.2 g of water in a coffee-cup calorimeter the temperature rises from 20.00 oC to 34.77 oC. Calculate H in kJ/mol NaOH for the solution process.
NaOH(s) Na+(aq) + OH-(aq)
The specific heat of water is 4.18 J/g-K.
Hsolution =______ kJ/mol NaOH.
Expert Solution
Step 1 introduction
In a coffee cup calorimeter
Amount of heat released due to reaction is equal to heat abosorbed by solution
qrxn = - qsolution
Now heat abosorbed by solution can be calculated by
qsol = - msol x Ssol x ∆Tsol
Where
msol = mass of solute + mass of solvent
= 2.45 g + 41.2 g
= 43.65 g
S = specific heat = 4.18 J/g K
∆T sol = ( 307.77 K - 293 K)
= 14.77 K
Where 0°C = 273 K
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