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What two diastereomer products would you expect for the reduction of the ketone below? Name both compounds, including the absolute stereochemistry (R,S) at each stereo center. он нс CHЗ R -CHз Нас CH3 R Нас Minor CH3 -CHз 1. NABH, Нас CHз Нас Нас OH Major -CHз R Hас CH3 Decide which diastereomer would likely be in excess using NaBH4 as the reducing agent. The most stable product would be the one that minimizes gauche interactions for the largest groups. The relative size of the groups might be counterintuitive. To be more certain you can look up "A values" to

What two diastereomer products would you expect for the reduction of the ketone below? Name both compounds, including the absolute stereochemistry (R,S) at each stereo center. он нс CHЗ R -CHз Нас CH3 R Нас Minor CH3 -CHз 1. NABH, Нас CHз Нас Нас OH Major -CHз R Hас CH3 Decide which diastereomer would likely be in excess using NaBH4 as the reducing agent. The most stable product would be the one that minimizes gauche interactions for the largest groups. The relative size of the groups might be counterintuitive. To be more certain you can look up "A values" to

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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What two diastereomer products would you expect for the reduction of the ketone below? Name both compounds, including the absolute stereochemistry (R,S) at each stereo center. он нс CHЗ R -CHз Нас CH3 R Нас Minor CH3 -CHз 1. NABH, Нас CHз Нас Нас OH Major -CHз R Hас CH3 Decide which diastereomer would likely be in excess using NaBH4 as the reducing agent. The most stable product would be the one that minimizes gauche interactions for the largest groups. The relative size of the groups might be counterintuitive. To be more certain you can look up "A values" to
Transcribed Image Text:What two diastereomer products would you expect for the reduction of the ketone below? Name both compounds, including the absolute stereochemistry (R,S) at each stereo center. он нс CHЗ R -CHз Нас CH3 R Нас Minor CH3 -CHз 1. NABH, Нас CHз Нас Нас OH Major -CHз R Hас CH3 Decide which diastereomer would likely be in excess using NaBH4 as the reducing agent. The most stable product would be the one that minimizes gauche interactions for the largest groups. The relative size of the groups might be counterintuitive. To be more certain you can look up "A values" to
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