What two diastereomer products would you expect for the reduction of the ketone below? Name both compounds, including the absolute stereochemistry (R,S) at each stereo center. он нс CHЗ R -CHз Нас CH3 R Нас Minor CH3 -CHз 1. NABH, Нас CHз Нас Нас OH Major -CHз R Hас CH3 Decide which diastereomer would likely be in excess using NaBH4 as the reducing agent. The most stable product would be the one that minimizes gauche interactions for the largest groups. The relative size of the groups might be counterintuitive. To be more certain you can look up "A values" to
What two diastereomer products would you expect for the reduction of the ketone below? Name both compounds, including the absolute stereochemistry (R,S) at each stereo center. он нс CHЗ R -CHз Нас CH3 R Нас Minor CH3 -CHз 1. NABH, Нас CHз Нас Нас OH Major -CHз R Hас CH3 Decide which diastereomer would likely be in excess using NaBH4 as the reducing agent. The most stable product would be the one that minimizes gauche interactions for the largest groups. The relative size of the groups might be counterintuitive. To be more certain you can look up "A values" to
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
Related questions
Question
name the two compunds
NO EQUATION IS GIVEN.
Transcribed Image Text:What two diastereomer products would you expect for the reduction of the ketone below? Name
both compounds, including the absolute stereochemistry (R,S) at each stereo center.
он нс
CHЗ
R
-CHз
Нас
CH3
R
Нас
Minor
CH3
-CHз
1. NABH,
Нас
CHз
Нас
Нас
OH
Major
-CHз
R
Hас
CH3
Decide which diastereomer would likely be in excess using NaBH4 as the reducing agent. The most
stable product would be the one that minimizes gauche interactions for the largest groups. The
relative size of the groups might be counterintuitive. To be more certain you can look up "A values" to
Expert Solution
This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
This is a popular solution!
Trending now
This is a popular solution!
Step by step
Solved in 2 steps with 1 images
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Recommended textbooks for you
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY