Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
Related questions
Question
what is C2-C3 bond and what is C1-C2 bond?how does breaking C2-C3 bond gives ch3-ch2?what is the mechanism?

Transcribed Image Text:C
propyl cation CH-CH₂-CH3
not a butyl cation CH₂-CH₂-CH₂-CH
Answer: Let's
compare CH₂ - CH₂ - CH₂ VS CH₂-CH₂-CH₂-CH₂
CH₂-CH₂ &
CH₂-CH₂-CH₂
breaking C2-C3 bond gives
• breaking C1-C2 bond gives CH & CH₂ - CH₂ - CH₂ - CH₂
situation leads to formation of more
ions ?
.
Question 1: Why is
peak
base
the
which
C2 C3
stable
->>>
C1 C2->>
CH₂ - CH₂
primary (1Jethyl
cation
+
CH₂
methyl cation
the least stable fragment
less stable
is
to
easier
CH₂-CH₂-CH₂
primary (19) propyl
cation
+
CH₂ CH₂-CH₂-CH₂
1 bytel cation
than (1) primary
CHỌĐ carbocation
break
carbocation. It is
C2 food because this produces more
C2-C3 bond than
stable 19 carbo -
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