What color would I expect a solution of dichromate ions to be after I add an excess of base? Briefly explain.

Chemistry
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**Question 4:**

What color would I expect a solution of dichromate ions to be after I add an excess of base? Briefly explain.

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**Explanation:**

When an excess of base is added to a solution containing dichromate ions, the dichromate (\( \text{Cr}_2\text{O}_7^{2-} \)) ions convert to chromate (\( \text{CrO}_4^{2-} \)) ions. This is due to the increase in pH, which favors the chromate ion form. The color of the solution changes from orange (dichromate) to yellow (chromate). 

This color change is a classic demonstration of the equilibrium:

\[ \text{Cr}_2\text{O}_7^{2-} + \text{OH}^- \rightleftharpoons 2\text{CrO}_4^{2-} + \text{H}_2\text{O} \]

Thus, in an alkaline medium, one should expect the solution to be yellow.
Transcribed Image Text:**Question 4:** What color would I expect a solution of dichromate ions to be after I add an excess of base? Briefly explain. --- **Explanation:** When an excess of base is added to a solution containing dichromate ions, the dichromate (\( \text{Cr}_2\text{O}_7^{2-} \)) ions convert to chromate (\( \text{CrO}_4^{2-} \)) ions. This is due to the increase in pH, which favors the chromate ion form. The color of the solution changes from orange (dichromate) to yellow (chromate). This color change is a classic demonstration of the equilibrium: \[ \text{Cr}_2\text{O}_7^{2-} + \text{OH}^- \rightleftharpoons 2\text{CrO}_4^{2-} + \text{H}_2\text{O} \] Thus, in an alkaline medium, one should expect the solution to be yellow.
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