What are the configurations of the two stereogenic carbon atoms in this molecule? CI H 5 60 3 2 4 H3C H A. (3R, 6R) B. (3R, 6S) OC. (3S, 6R) OD. (3S, 6S)
What are the configurations of the two stereogenic carbon atoms in this molecule? CI H 5 60 3 2 4 H3C H A. (3R, 6R) B. (3R, 6S) OC. (3S, 6R) OD. (3S, 6S)
Chemistry: Matter and Change
1st Edition
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Chapter21: Hydrocarbons
Section: Chapter Questions
Problem 79A
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![**Question:**
What are the configurations of the two stereogenic carbon atoms in this molecule?
[Diagram]
- The diagram depicts a six-membered ring with various substituents:
- A chlorine atom (Cl) attached to carbon 1.
- A hydrogen atom (H) is also bonded to carbon 1 in a wedge configuration.
- An oxygen atom (O) is shown in the ring.
- A methyl group (CH₃) attached to carbon 4.
- The ring is numbered from 1 to 6 starting from the top-right carbon and proceeding clockwise.
**Options:**
A. (3R, 6R)
B. (3R, 6S)
C. (3S, 6R)
D. (3S, 6S)](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F07b5422f-b762-4b45-b34e-ddb9cce4666f%2F906e3f25-ac91-4502-8999-2c937beb392b%2F7g3n2h8_processed.jpeg&w=3840&q=75)
Transcribed Image Text:**Question:**
What are the configurations of the two stereogenic carbon atoms in this molecule?
[Diagram]
- The diagram depicts a six-membered ring with various substituents:
- A chlorine atom (Cl) attached to carbon 1.
- A hydrogen atom (H) is also bonded to carbon 1 in a wedge configuration.
- An oxygen atom (O) is shown in the ring.
- A methyl group (CH₃) attached to carbon 4.
- The ring is numbered from 1 to 6 starting from the top-right carbon and proceeding clockwise.
**Options:**
A. (3R, 6R)
B. (3R, 6S)
C. (3S, 6R)
D. (3S, 6S)
Expert Solution
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Step 1
Priority order is given to the different groups and atoms attached to the stereogenic carbon carbon. The fourth priority atom or group must be present in the dash line. If the other three groups or atoms are ordered in a clockwise manner, the absolute configuration is R and if the order of the atoms or groups is anticlockwise, the configuration is S.
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