Vol NaOH added Hd

Advanced Engineering Mathematics
10th Edition
ISBN:9780470458365
Author:Erwin Kreyszig
Publisher:Erwin Kreyszig
Chapter2: Second-order Linear Odes
Section: Chapter Questions
Problem 1RQ
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When a diprotic acid, H2A, is titrated with NaOH, the protons on the diprotic acid are generally removed one at a time, resulting in a pH curve that has the following generic shape:

a.Notice that the plot has essentially two titration curves. If the first equivalence point occurs at 100.0 mL NaOH added, what volume of NaOH added corresponds to the second equivalence point?

b.For the following volumes of NaOH added, list the major species present after the OH- reacts completely.

i.0 mL NaOH added

ii.between 0 and 100.0 mL NaOH added

iii.100.0 mL NaOH added

iv.between 100.0 and 200.0 mL NaOH added

v.200.0 mL NaOH added

vi. after 200.0 mL NaOH added

If the pH at 50.0 mL NaOH added is 4.0, and the pH at 150.0 mL NaOH added is 8.0, determine the values Ka1 and Ka2 for the diprotic acid.

Vol NaOH added
Hd
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