(vii) Addition of 51.00 mL of TI3*. (viii) Addition of 60.00 mL of TI3+. Use a graph paper and construct a titration curve for the redox titration in

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
Publisher:Skoog
Chapter26: Molecular Absorption Spectrometry
Section: Chapter Questions
Problem 26.20QAP
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ONLY ANSWER (vii) (viii) (B)

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(a) Calculate the potential after the addition of the following volume of 10.00, 25.00,
49.00, 49.90, 50.00, 50.10, 51.00 and 60.00 mL of 0.0500 M TI3+ with 50.00 mL of
0.100 M Fe(CN)6“.
Es+ TI*
+1.25 V; Ee(cN):-/Fe(CN);
= +0.36 V
(i)
Addition of 10.00 mL of TI3+.
(ii)
Addition of 25.00 mL of TI3+.
2.
Transcribed Image Text:(a) Calculate the potential after the addition of the following volume of 10.00, 25.00, 49.00, 49.90, 50.00, 50.10, 51.00 and 60.00 mL of 0.0500 M TI3+ with 50.00 mL of 0.100 M Fe(CN)6“. Es+ TI* +1.25 V; Ee(cN):-/Fe(CN); = +0.36 V (i) Addition of 10.00 mL of TI3+. (ii) Addition of 25.00 mL of TI3+. 2.
(ii)
Addition of 49.00 mL of TI3+.
(iv) Addition of 49.90 mL of T13+.
(v)
Addition of 50.00 mL of TI3+.
(vi) Addition of 50.10 mL of T13+.
(vii) Addition of 51.00 mL of T|3*.
(viii) Addition of 60.00 mL of TI3*.
(b) Use a graph paper and construct a titration curve for the redox titration in 2(a).
Transcribed Image Text:(ii) Addition of 49.00 mL of TI3+. (iv) Addition of 49.90 mL of T13+. (v) Addition of 50.00 mL of TI3+. (vi) Addition of 50.10 mL of T13+. (vii) Addition of 51.00 mL of T|3*. (viii) Addition of 60.00 mL of TI3*. (b) Use a graph paper and construct a titration curve for the redox titration in 2(a).
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