Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:You will need to use the unfilled (unpopulated) molecular-orbital (MO) diagram for a homonuclear diatomic molecule or ion, such as O₂, F₂, O₂⁺, F₂⁺, O₂⁻, F₂⁻.
IMPORTANT: This diagram includes only valence orbitals.
### Diagram Explanation:
- The diagram consists of molecular orbitals, represented by lines and labels, indicating their energy levels.
- The left and right sides of the diagram show the atomic orbitals (2s and 2p) of two atoms.
- In the center, the molecular orbitals are depicted:
- \(\sigma_{2s}\)
- \(\sigma^*_{2s}\)
- \(\sigma_{2p}\)
- \(\pi_{2p}\), \(\pi_{2p}\)
- \(\pi^*_{2p}\), \(\pi^*_{2p}\)
- \(\sigma^*_{2p}\)
Using scratch paper, complete this diagram specifically for the \(O_2^-\) molecular anion, indicating the electron populations for all valence molecular orbitals. Using the completed diagram, answer the question: What is the bond order in \(O_2^-\)?
- Options for bond order:
- 0
- 0.5
- 1
- 1.5
- 2
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