Using the table for lonic Radii for Several Cations and Anions c. Cell edge length of ferrous oxide which has a rock salt structure. Compare the cell edge length if the density of ferrous oxide is 5.75g/cm.

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IONIC RADII FOR SEVERAL CATIONS ANS ANIONS FOR COORDINATION NUMBER 6
Ionic
Ionic
Cation
Radius (nm)
Anion
Radius (nm)
13+
0.053
Br
0.196
Ba2+
0.136
CI-
0.181
Ca²+
0.100
F
0.133
Cs*
0.170
0.220
Fe2+
0.077
O²-
0.140
Fe3+
0.069
S2-
0.184
K+
0.138
Mg2+
0.072
Mn²+
0.067
Na+
0.102
Ni2+
0.069
Sit+
0.040
Tit+
0.061
Table 12.4 Summary of Some Common Ceramic Crystal Structures
Coordination
Number
Structure
Anion Packing
Cation
Structure Name
Туре
Anion
Examples
Rock salt (sodium chloride)
AX
FCC
6
6.
NaCl, MgO, FeO
Cesium chloride
AX
Simple cubic
8
8
CSCI
Zinc blende (sphalerite)
AX
FCC
4
4
ZnS, SiC
Fluorite
AX,
Simple cubic
8
4
CaF2, UO, ThO,
Perovskite
АВХ,
FCC
12 (A)
6 (B)
6.
BaTiO3, SrZrO3, SrSnO;
4 (A)
6 (B)
Spinel
AB,X,
FCC
4
MgAl,O,, FeAl,O,
Source: W. D. Kingery, H. K. Bowen, and D. R. Uhlmann, Introduction to Ceramics, 2nd edition. Copyright © 1976 by John Wiley &
Sons, New York. Reprinted by permission of John Wiley & Sons, Inc.
Transcribed Image Text:IONIC RADII FOR SEVERAL CATIONS ANS ANIONS FOR COORDINATION NUMBER 6 Ionic Ionic Cation Radius (nm) Anion Radius (nm) 13+ 0.053 Br 0.196 Ba2+ 0.136 CI- 0.181 Ca²+ 0.100 F 0.133 Cs* 0.170 0.220 Fe2+ 0.077 O²- 0.140 Fe3+ 0.069 S2- 0.184 K+ 0.138 Mg2+ 0.072 Mn²+ 0.067 Na+ 0.102 Ni2+ 0.069 Sit+ 0.040 Tit+ 0.061 Table 12.4 Summary of Some Common Ceramic Crystal Structures Coordination Number Structure Anion Packing Cation Structure Name Туре Anion Examples Rock salt (sodium chloride) AX FCC 6 6. NaCl, MgO, FeO Cesium chloride AX Simple cubic 8 8 CSCI Zinc blende (sphalerite) AX FCC 4 4 ZnS, SiC Fluorite AX, Simple cubic 8 4 CaF2, UO, ThO, Perovskite АВХ, FCC 12 (A) 6 (B) 6. BaTiO3, SrZrO3, SrSnO; 4 (A) 6 (B) Spinel AB,X, FCC 4 MgAl,O,, FeAl,O, Source: W. D. Kingery, H. K. Bowen, and D. R. Uhlmann, Introduction to Ceramics, 2nd edition. Copyright © 1976 by John Wiley & Sons, New York. Reprinted by permission of John Wiley & Sons, Inc.
Using the table for lonic Radii for Several Cations and Anions
c. Cell edge length of ferrous oxide which has a rock salt structure. Compare the cell edge length if the
density of ferrous oxide is 5.75g/cm?.
Transcribed Image Text:Using the table for lonic Radii for Several Cations and Anions c. Cell edge length of ferrous oxide which has a rock salt structure. Compare the cell edge length if the density of ferrous oxide is 5.75g/cm?.
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