Using the Lewis concept of acids and bases, identify the Lewis acid and base in each of the following reactions: Fe(NO3), (s) + 6H,0(1)→Fe(H,O)," (aq) + 3NO, (aq) (CH3),NH(g) + HF(g)(CH3),NH2F(s)

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Lewis concept
A Lewis acid is an electron-pair acceptor, and a Lewis base is an electron-pair donor.
A substance that accepts an electron pair is an acid, such as Fe+ in this example where a pair of electrons on CN- is transferred to the metal:
Fet (aq) + 6CN (aq) → Fe(CN)63 (aq)
A substance that donates an electron-pair is a base, such as water in this example where a pair of electrons on the oxygen of water are transferred to the metal cation core:
Fe(H2O)5]?+ (aq) + H2O(1) = Fe(H2O)6]3+ (aq)
The Lewis concept greatly increases the number of species that can be thought of as acids and bases. It allows cations and species with incomplete octets to be defined as an acid. You can identify a transition
metal cation that act as acids by assessing whether a ligand with transferable electrons donates electrons to the metal core.
Part C
Using the Lewis concept of acids and bases, identify the Lewis acid and base in each of the following reactions:
Fe(NO3)3(s) + 6H,0(1)¬Fe(H2O),* (aq) + 3NO3 (aq)
(CH3),NH(g) + HF(g)→(CH3),NH2F(s)
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Fe(NO3)3
H20
(CH3)2NH
HF
Lewis acid
Lewis base
Neither
Submit
Transcribed Image Text:Lewis concept A Lewis acid is an electron-pair acceptor, and a Lewis base is an electron-pair donor. A substance that accepts an electron pair is an acid, such as Fe+ in this example where a pair of electrons on CN- is transferred to the metal: Fet (aq) + 6CN (aq) → Fe(CN)63 (aq) A substance that donates an electron-pair is a base, such as water in this example where a pair of electrons on the oxygen of water are transferred to the metal cation core: Fe(H2O)5]?+ (aq) + H2O(1) = Fe(H2O)6]3+ (aq) The Lewis concept greatly increases the number of species that can be thought of as acids and bases. It allows cations and species with incomplete octets to be defined as an acid. You can identify a transition metal cation that act as acids by assessing whether a ligand with transferable electrons donates electrons to the metal core. Part C Using the Lewis concept of acids and bases, identify the Lewis acid and base in each of the following reactions: Fe(NO3)3(s) + 6H,0(1)¬Fe(H2O),* (aq) + 3NO3 (aq) (CH3),NH(g) + HF(g)→(CH3),NH2F(s) Drag the appropriate items to their respective bins. • View Available Hint(s) Reset Help Fe(NO3)3 H20 (CH3)2NH HF Lewis acid Lewis base Neither Submit
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