Using reactions chosen from the Full Terpene Biosynthesis Toolkit (shown below), provide a plausible biosynthetic pathway, including curly arrow mechanisms (except for redox steps), from DMAPP and IPP to the terpene shown below. OPP DMAPP IPP OPP multiple steps OH 人 Full Terpene Biosynthesis Toolkit: . Initiation by loss of OPP. Initiation by protonation of an alkene. Propagation by resonance. Propagation by addition of an alkene.. Propagation by Wagner-Meerwein rearrangement. ■ Termination by addition of a nucleophile. • Termination by elimination. • Termination by 1,3-deprotonation. Hydrolysis of OPP to an OH group. OH

Using reactions chosen from the Full Terpene Biosynthesis Toolkit (shown below), provide a plausible biosynthetic pathway, including curly arrow mechanisms (except for redox steps), from DMAPP and IPP to the terpene shown below. OPP DMAPP IPP OPP multiple steps OH 人 Full Terpene Biosynthesis Toolkit: . Initiation by loss of OPP. Initiation by protonation of an alkene. Propagation by resonance. Propagation by addition of an alkene.. Propagation by Wagner-Meerwein rearrangement. ■ Termination by addition of a nucleophile. • Termination by elimination. • Termination by 1,3-deprotonation. Hydrolysis of OPP to an OH group. OH

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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