Using data from the Standard Reduction Potentials table, place the following in order of increasing strength as reducing agents (all under standard conditions). (Use the appropriate <, =, or > symbol to separate substances in the list.) Br-, Fe²+, Fe, MnO₂, PbSO4, and 103
Using data from the Standard Reduction Potentials table, place the following in order of increasing strength as reducing agents (all under standard conditions). (Use the appropriate <, =, or > symbol to separate substances in the list.) Br-, Fe²+, Fe, MnO₂, PbSO4, and 103
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question
![Using data from the Standard Reduction Potentials table, place the following in order of increasing strength as reducing
agents (all under standard conditions). (Use the appropriate <, =, or > symbol to separate substances in the list.)
Br, Fe²+, Fe, MnO₂, PbSO4 and IO3
chemPad
X₁X⁰
Help
Greek](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fbc49b70e-3bee-4d78-855e-9a8fe26fc256%2F0453e371-56c4-425b-9c07-6eec2a473db0%2Fcmoemq_processed.png&w=3840&q=75)
Transcribed Image Text:Using data from the Standard Reduction Potentials table, place the following in order of increasing strength as reducing
agents (all under standard conditions). (Use the appropriate <, =, or > symbol to separate substances in the list.)
Br, Fe²+, Fe, MnO₂, PbSO4 and IO3
chemPad
X₁X⁰
Help
Greek
![Standard Reduction Potentials at 25°C (298 K) for Many Common Half-reactions
8° (V)
Half-reaction
Half-reaction
F₂ +2e2F-
Ag²+ + e- → Ag+
Co³+ + e→→ Co²+
H₂O₂ + 2H+ + 2e → 2H₂O
Ce++e
Ce³+
PbO₂ + 4H+ + SO4²- + 2e¯ → PbSO4 + 2H₂O
MnO4 + 4H+ + 3e¯ → MnO₂ + 2H₂O
IO4 + 2H+ + 2e¯ → IO3 + H₂O
MnO4 + 8H+ + 5e¯ → Mn²+ + 4H₂O
Au³+ + 3e →→ Au
PbO₂ + 4H+ + 2e¯ → Pb²+ + 2H₂O
Cl₂ +2e2C1-
Cr₂O7²- + 14H+ + 6e¯ → 2Cr³+ + 7H₂O
O₂ + 4H+ + 4e¯ → 2H₂O
MnO₂ + 4H+ + 2e → Mn²+ + 2H₂O
103 + 6H+ + Se¯ → 1₂+ 3H₂O
Br₂ +2e
2Br
VO₂+ + 2H+ + e¯ → VO²+ + H₂O
AuCl + 3e → Au + 4Cl-
NO3 + 4H+ + 3e¯ → NO + 2H₂O
CIO₂ + e → CIO₂
2Hg²+ + 2e →→ Hg₂²+
Ag+ e → Ag
Hg₂²+ + 2e → 2Hg
Fe³+ + e Fe²+
O₂ + 2H+ + 2e™ → H₂O₂
MnO4 + e→→ MnO4²-
1₂ +2e → 21
Cute Cu
2.87
1.99
1.82
1.78
1.70
1.69
1.68
1.60
1.51
1.50
1.46
1.36
1.33
1.23
1.21
1.20
1.09
1.00
0.99
0.96
0.954
0.91
0.80
0.80
0.77
0.68
0.56
0.54
0.52
O₂ + 2H₂O + 4e¯ → 40H-
Cu²+ + 2e → Cu
Hg₂Cl₂ + 2e
AgCl + e →
SO4²- + 4H+
Cu²+ + e→→
2H+ + 2e
Fe³+ + 3e
Pb²+ + 2e
Sn²+ + 2e
Ni²+ + 2e
PbSO4 + 2e
Cd²+ + 2e
Fe²++2e
Cr³+ + e
Cr³+ + 3e
→ 2Hg + 2C1-
Ag + Cl-
+ 2e¯ → H₂SO3 + H₂O
Cut
H₂
Fe
→→ Pb
→→ Sn
→→ Ni
→ Pb + SO4²-
→→ Cd.
Fe
Cr2+
Cr
→→→ Zn
→→ H₂ + 2OH-
Zn²+ + 2e
2H₂O + 2e
Mn²+ + 2e→→ Mn
Al³+ + 3e →→ Al
H₂ + 2e → 2H-
Mg²+ + 2e
La³+ + 3e →→ La
Na+ +e →→→ Na
Ca²+ + 2e →→ Ca
Ba²+2e→→→ Ba
→ Mg
K++e → K
Li + e™ → Li
8° (V)
0.40
0.34
0.27
0.22
0.20
0.16
0.00
-0.036
-0.13
-0.14
-0.23
-0.35
-0.40
-0.44
-0.50
-0.73
-0.76
-0.83
-1.18
-1.66
-2.23
-2.37
-2.37
-2.71
-2.76
-2.90
-2.92
-3.05](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fbc49b70e-3bee-4d78-855e-9a8fe26fc256%2F0453e371-56c4-425b-9c07-6eec2a473db0%2F14stpca_processed.png&w=3840&q=75)
Transcribed Image Text:Standard Reduction Potentials at 25°C (298 K) for Many Common Half-reactions
8° (V)
Half-reaction
Half-reaction
F₂ +2e2F-
Ag²+ + e- → Ag+
Co³+ + e→→ Co²+
H₂O₂ + 2H+ + 2e → 2H₂O
Ce++e
Ce³+
PbO₂ + 4H+ + SO4²- + 2e¯ → PbSO4 + 2H₂O
MnO4 + 4H+ + 3e¯ → MnO₂ + 2H₂O
IO4 + 2H+ + 2e¯ → IO3 + H₂O
MnO4 + 8H+ + 5e¯ → Mn²+ + 4H₂O
Au³+ + 3e →→ Au
PbO₂ + 4H+ + 2e¯ → Pb²+ + 2H₂O
Cl₂ +2e2C1-
Cr₂O7²- + 14H+ + 6e¯ → 2Cr³+ + 7H₂O
O₂ + 4H+ + 4e¯ → 2H₂O
MnO₂ + 4H+ + 2e → Mn²+ + 2H₂O
103 + 6H+ + Se¯ → 1₂+ 3H₂O
Br₂ +2e
2Br
VO₂+ + 2H+ + e¯ → VO²+ + H₂O
AuCl + 3e → Au + 4Cl-
NO3 + 4H+ + 3e¯ → NO + 2H₂O
CIO₂ + e → CIO₂
2Hg²+ + 2e →→ Hg₂²+
Ag+ e → Ag
Hg₂²+ + 2e → 2Hg
Fe³+ + e Fe²+
O₂ + 2H+ + 2e™ → H₂O₂
MnO4 + e→→ MnO4²-
1₂ +2e → 21
Cute Cu
2.87
1.99
1.82
1.78
1.70
1.69
1.68
1.60
1.51
1.50
1.46
1.36
1.33
1.23
1.21
1.20
1.09
1.00
0.99
0.96
0.954
0.91
0.80
0.80
0.77
0.68
0.56
0.54
0.52
O₂ + 2H₂O + 4e¯ → 40H-
Cu²+ + 2e → Cu
Hg₂Cl₂ + 2e
AgCl + e →
SO4²- + 4H+
Cu²+ + e→→
2H+ + 2e
Fe³+ + 3e
Pb²+ + 2e
Sn²+ + 2e
Ni²+ + 2e
PbSO4 + 2e
Cd²+ + 2e
Fe²++2e
Cr³+ + e
Cr³+ + 3e
→ 2Hg + 2C1-
Ag + Cl-
+ 2e¯ → H₂SO3 + H₂O
Cut
H₂
Fe
→→ Pb
→→ Sn
→→ Ni
→ Pb + SO4²-
→→ Cd.
Fe
Cr2+
Cr
→→→ Zn
→→ H₂ + 2OH-
Zn²+ + 2e
2H₂O + 2e
Mn²+ + 2e→→ Mn
Al³+ + 3e →→ Al
H₂ + 2e → 2H-
Mg²+ + 2e
La³+ + 3e →→ La
Na+ +e →→→ Na
Ca²+ + 2e →→ Ca
Ba²+2e→→→ Ba
→ Mg
K++e → K
Li + e™ → Li
8° (V)
0.40
0.34
0.27
0.22
0.20
0.16
0.00
-0.036
-0.13
-0.14
-0.23
-0.35
-0.40
-0.44
-0.50
-0.73
-0.76
-0.83
-1.18
-1.66
-2.23
-2.37
-2.37
-2.71
-2.76
-2.90
-2.92
-3.05
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