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Using any alkene and any reagents necessary, how would you prepare the following compound?

Using any alkene and any reagents necessary, how would you prepare the following compound?

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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**Preparation of 1-Hexanol:** **Problem Statement:** Using any alkene and any reagents necessary, how would you prepare the following compound? **Target Compound Structure:** - The structure shown in the image is 1-Hexanol, which is a linear alcohol with six carbon atoms. **Synthesis Explanation:** To synthesize 1-Hexanol, you can start with hexene, an alkene with a six-carbon chain. A common method is the hydration of hexene to convert it into 1-Hexanol. Here is a potential synthesis pathway: 1. **Starting Material:** - Use 1-hexene (C₆H₁₂) as the starting alkene. 2. **Reaction Steps:** 1. **Hydroboration-Oxidation:** - **Reagents:** - Borane (BH₃) or a borane complex like diborane (B₂H₆) or BH₃-THF for hydroboration. - Hydrogen peroxide (H₂O₂) and sodium hydroxide (NaOH) for oxidation. - **Procedure:** - React 1-hexene with borane to form trialkylborane in an anti-Markovnikov addition. - Oxidize the trialkylborane with H₂O₂ in the presence of NaOH to convert the boron group into a hydroxyl group, yielding 1-Hexanol. By using the hydroboration-oxidation method, you ensure the hydroxyl group is added to the less substituted carbon, resulting in a primary alcohol like 1-Hexanol.
Transcribed Image Text:**Preparation of 1-Hexanol:** **Problem Statement:** Using any alkene and any reagents necessary, how would you prepare the following compound? **Target Compound Structure:** - The structure shown in the image is 1-Hexanol, which is a linear alcohol with six carbon atoms. **Synthesis Explanation:** To synthesize 1-Hexanol, you can start with hexene, an alkene with a six-carbon chain. A common method is the hydration of hexene to convert it into 1-Hexanol. Here is a potential synthesis pathway: 1. **Starting Material:** - Use 1-hexene (C₆H₁₂) as the starting alkene. 2. **Reaction Steps:** 1. **Hydroboration-Oxidation:** - **Reagents:** - Borane (BH₃) or a borane complex like diborane (B₂H₆) or BH₃-THF for hydroboration. - Hydrogen peroxide (H₂O₂) and sodium hydroxide (NaOH) for oxidation. - **Procedure:** - React 1-hexene with borane to form trialkylborane in an anti-Markovnikov addition. - Oxidize the trialkylborane with H₂O₂ in the presence of NaOH to convert the boron group into a hydroxyl group, yielding 1-Hexanol. By using the hydroboration-oxidation method, you ensure the hydroxyl group is added to the less substituted carbon, resulting in a primary alcohol like 1-Hexanol.
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