Use the given bond energy values to estimate ΔH for the following gas-phase reaction. (Simple energy units required for the answer.) D-values in kJ/mol DH-H = 432 DH-Br = 363 DH-C = 413 DH-N = 391 DH-O = 467 DC-C = 347 DC=C = 614 DC≡C = 839 DC-N = 305 DC=N = 615 DC≡N = 891 DC-O = 358 DC=O = 745 DC=O (CO2) = 799 DC≡O=1072 DC-Br = 276 DN-N = 160. DN=N = 418 DN≡N = 941 DO-O = 146 DO=O = 495 DN-O = 201 DN=O = 607 DBr-Br = 193 DC-Cl = 339 DH-Cl = 427 DCl-Cl = 239
Thermochemistry
Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.
Exergonic Reaction
The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.
Use the given bond energy values to estimate ΔH for the following gas-phase reaction.
(Simple energy units required for the answer.) |
D-values in kJ/mol
DH-H = 432 | DH-Br = 363 | DH-C = 413 |
DH-N = 391 | DH-O = 467 | DC-C = 347 |
DC=C = 614 | DC≡C = 839 | DC-N = 305 |
DC=N = 615 | DC≡N = 891 | DC-O = 358 |
DC=O = 745 | DC=O (CO2) = 799 | DC≡O=1072 |
DC-Br = 276 | DN-N = 160. | DN=N = 418 |
DN≡N = 941 | DO-O = 146 | DO=O = 495 |
DN-O = 201 | DN=O = 607 | DBr-Br = 193 |
DC-Cl = 339 | DH-Cl = 427 | DCl-Cl = 239 |


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