Use Cahn-Ingold-Prelog rules on the molecule below and highlight the highest priority substituent red, second priority blue, and third priority green. In your answer, be sure to highlight the entire substituent. Key: 1 (Highest Priority) = Red 2 (Second Priority) = Blue 3 (Third Priority) = Green Explanation Check X 3
Reactive Intermediates
In chemistry, reactive intermediates are termed as short-lived, highly reactive atoms with high energy. They rapidly transform into stable particles during a chemical reaction. In specific cases, by means of matrix isolation and at low-temperature reactive intermediates can be isolated.
Hydride Shift
A hydride shift is a rearrangement of a hydrogen atom in a carbocation that occurs to make the molecule more stable. In organic chemistry, rearrangement of the carbocation is very easily seen. This rearrangement can be because of the movement of a carbocation to attain stability in the compound. Such structural reorganization movement is called a shift within molecules. After the shifting of carbocation over the different carbon then they form structural isomers of the previous existing molecule.
Vinylic Carbocation
A carbocation where the positive charge is on the alkene carbon is known as the vinyl carbocation or vinyl cation. The empirical formula for vinyl cation is C2H3+. In the vinyl carbocation, the positive charge is on the carbon atom with the double bond therefore it is sp hybridized. It is known to be a part of various reactions, for example, electrophilic addition of alkynes and solvolysis as well. It plays the role of a reactive intermediate in these reactions.
Cycloheptatrienyl Cation
It is an aromatic carbocation having a general formula, [C7 H7]+. It is also known as the aromatic tropylium ion. Its name is derived from the molecule tropine, which is a seven membered carbon atom ring. Cycloheptatriene or tropylidene was first synthesized from tropine.
Stability of Vinyl Carbocation
Carbocations are positively charged carbon atoms. It is also known as a carbonium ion.
Chiral carbon is the one in which the carbon is bonded to four different groups.
Absolute configuration is assigned to the chiral carbon.
To assign configuration, we need to give priority to the groups that are bonded to chiral carbon.
This is done by using CIP rules.
According to CIP rules,
(1)Group with highest atomic number gets higher priority
(2)If any two groups have identical atoms, we should compare the next atoms that is bonded to first carbon.
(3)If a double bond is present, it is considered as two carbons.
(4)If a triple bond is present, it is considered as three carbons.
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