Uranium-233 decays to thorium-229 by α decay, but the emissions have different energies and products: 83% emit an α particle with energy of 4.816 MeV and give 229Th in its groundstate; 15% emit an α particle of 4.773 MeV and give 229Th in ex-cited state I; and 2% emit a lower energy α particle and give 229Th in the higher excited state II. Excited state II emits a γ ray of 0.060 MeV to reach excited state I. (a) Find the γ ray energyand wavelength that would convert excited state I to the groundstate. (b) Find the energy of the α particle that would convert 233U to excited state II.

Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Uranium-233 decays to thorium-229 by α decay, but the emissions have different energies and products: 83% emit an α particle with energy of 4.816 MeV and give 229Th in its groundstate; 15% emit an α particle of 4.773 MeV and give 229Th in ex-cited state I; and 2% emit a lower energy α particle and give 229Th in the higher excited state II. Excited state II emits a γ ray of 0.060 MeV to reach excited state I. (a) Find the γ ray energyand wavelength that would convert excited state I to the groundstate. (b) Find the energy of the α particle that would convert 233U to excited state II.

Expert Solution
Step 1

The relationship between energy and wavelength of the light is expressed as,

E=hcλ......(1)

Where,

  • h is Planck's constant.
  • c is the speed of light.
  • λ is the wavelength of the light.
Step 2

(a)

The energy of the gamma-ray that converts excited state I to the ground state is calculated by the formula,

Eγ=E1-E2

Where,

  • E1 is the energy of the alpha-particle emitted by 83% of decay.
  • E2 is the energy of the alpha-particle emitted by 15% of decay.

Substitute the energy of alpha-particles emitted by 83% and 15% of decay in the above formula.

Eγ=4.816 MeV-4.773 MeV=0.043 MeV

Step 3

Convert 0.043 MeV to eV.

0.043 MeV=0.043×106 eV=4.3×104 eV

Convert 4.3×104 eV to J.

4.3×104 eV=4.3×104×1.6022×10-19 J=6.88946×10-15 J

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