Unit I 1. (a) What is the effect of temperature on the rate of reaction? What are different theories for determination of temperature dependence of reaction rate? Explain in detail. 9 (b) At 500 K the rate of a bimolecular reaction is - 10 times the rate at 400 K. Find the activation energy for this reaction (i) from Arrhenius Law, (i) from collision theory, (ii) what is the percentage difference in rate of reaction at 600 K predicted by these two methods. 6 2. (a) What do you mean by integral and differential method of analysis of rate data? Explain in detail. What is difference between them? 9

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Unit I
1. (a) What is the effect of temperature on the rate of
reaction? What are different theories for
determination of temperature dependence of reaction
rate? Explain in detail.
9
(b) At 500 K the rate of a bimolecular reaction is
-
10 times the rate at 400 K. Find the activation
energy for this reaction (i) from Arrhenius Law,
(i) from collision theory, (ii) what is the percentage
difference in rate of reaction at 600 K predicted by
these two methods.
6
2. (a) What do you mean by integral and differential
method of analysis of rate data? Explain in detail.
What is difference between them?
9
Transcribed Image Text:Unit I 1. (a) What is the effect of temperature on the rate of reaction? What are different theories for determination of temperature dependence of reaction rate? Explain in detail. 9 (b) At 500 K the rate of a bimolecular reaction is - 10 times the rate at 400 K. Find the activation energy for this reaction (i) from Arrhenius Law, (i) from collision theory, (ii) what is the percentage difference in rate of reaction at 600 K predicted by these two methods. 6 2. (a) What do you mean by integral and differential method of analysis of rate data? Explain in detail. What is difference between them? 9
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