Une way in which the stoichiometry of a complex ion can be determined is by measuring the color intensities of solutions containing different proportions of the ligand and metal ion. In one such experiment, the maximum color intensity was observed when 5.2 cm³ of a 1 x 10³ M manganese ion solution and 1.56 cm³ of a 1 x 102 M solution of ethylenediamine were mixed. Given that one mole of a compound containing the complex ion from this mixture produces three moles of silver chloride when the compound reacts with excess silver nitrate, show whether the compound is diamagnetic or paramagnetic.

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter8: Bonding In Transition Metal Compounds And Coordination Complexes
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One way in which the stoichiometry of a complex ion can be determined is by measuring the
color intensities of solutions containing different proportions of the ligand and metal ion. In one
such experiment, the maximum color intensity was observed when 5.2 cm3³ of a 1 x 10³ M
manganese ion solution and 1.56 cm³ of a 1 x 102 M solution of ethylenediamine were mixed.
Given that one mole of a compound containing the complex ion from this mixture produces three
moles of silver chloride when the compound reacts with excess silver nitrate, show whether the
compound is diamagnetic or paramagnetic.
Transcribed Image Text:(b) One way in which the stoichiometry of a complex ion can be determined is by measuring the color intensities of solutions containing different proportions of the ligand and metal ion. In one such experiment, the maximum color intensity was observed when 5.2 cm3³ of a 1 x 10³ M manganese ion solution and 1.56 cm³ of a 1 x 102 M solution of ethylenediamine were mixed. Given that one mole of a compound containing the complex ion from this mixture produces three moles of silver chloride when the compound reacts with excess silver nitrate, show whether the compound is diamagnetic or paramagnetic.
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