Two moles of ethane in a piston-cylinder assembly undergo a reversible adiabatic compression from the initial volume of 0.1 m² to the final volume of 0.002 m³. The initial pressure is 0.5 bar. Note that if ideal gas, the heat capacity of ethane is given by Cp = 1.131 + 1.9225 x 10-² T-5.561 x 10-6 T², where T is in K. Use the van der Waals equation of state to determine (1) the initial temperature in K (also compares the result with that calculated using the ideal gas law), (2) the final pressure in bar, (3) the final temperature in K, and (4) the work done during this process in J.

Elements Of Electromagnetics
7th Edition
ISBN:9780190698614
Author:Sadiku, Matthew N. O.
Publisher:Sadiku, Matthew N. O.
ChapterMA: Math Assessment
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**Title: Adiabatic Compression of Ethane in a Piston-Cylinder Assembly**

**Overview:**
This problem involves two moles of ethane undergoing a reversible adiabatic compression in a piston-cylinder assembly. The initial volume of ethane is 0.1 m³, and it is compressed to a final volume of 0.002 m³. The initial pressure is 0.5 bar.

**Heat Capacity of Ethane:**
For ethane as an ideal gas, the heat capacity (\( \frac{c_p}{R} \)) is expressed as:
\[ \frac{c_p}{R} = 1.131 + 1.9225 \times 10^{-2} T - 5.561 \times 10^{-6} T^2 \]
where \( T \) is the temperature in Kelvin (K).

**Tasks:**
Use the van der Waals equation of state to determine:

1. **Initial Temperature:**
   Calculate the initial temperature in Kelvin using both the van der Waals equation and compare it with the result obtained using the ideal gas law.

2. **Final Pressure:**
   Determine the final pressure in bar once the compression is completed.

3. **Final Temperature:**
   Calculate the final temperature in Kelvin after the compression.

4. **Work Done:**
   Compute the work done during this adiabatic process, expressed in Joules (J).

This exercise provides insights into the behavior of real gases under non-ideal conditions, demonstrating the application of both the ideal gas law and the van der Waals equation for realistic approximations.
Transcribed Image Text:**Title: Adiabatic Compression of Ethane in a Piston-Cylinder Assembly** **Overview:** This problem involves two moles of ethane undergoing a reversible adiabatic compression in a piston-cylinder assembly. The initial volume of ethane is 0.1 m³, and it is compressed to a final volume of 0.002 m³. The initial pressure is 0.5 bar. **Heat Capacity of Ethane:** For ethane as an ideal gas, the heat capacity (\( \frac{c_p}{R} \)) is expressed as: \[ \frac{c_p}{R} = 1.131 + 1.9225 \times 10^{-2} T - 5.561 \times 10^{-6} T^2 \] where \( T \) is the temperature in Kelvin (K). **Tasks:** Use the van der Waals equation of state to determine: 1. **Initial Temperature:** Calculate the initial temperature in Kelvin using both the van der Waals equation and compare it with the result obtained using the ideal gas law. 2. **Final Pressure:** Determine the final pressure in bar once the compression is completed. 3. **Final Temperature:** Calculate the final temperature in Kelvin after the compression. 4. **Work Done:** Compute the work done during this adiabatic process, expressed in Joules (J). This exercise provides insights into the behavior of real gases under non-ideal conditions, demonstrating the application of both the ideal gas law and the van der Waals equation for realistic approximations.
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