Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![**Charge-Balance Equations for Solutions:**
a. **0.15 M in HF**
- \[ \text{[H}^+\text{]} = \text{[F}^-\text{]} + \text{[OH}^-\text{]} \]
b. **0.16 M in (CH₃)₂NH**
- \[ \text{[CH₃)₂NH₃}^+\text{]} + \text{[OH}^-\text{]} = \text{[CH₃)₂NH]} \]
c. **Saturated with Ag₂CO₃**
- \[ 2\text{[Ag}^+\text{]} + \text{[H}^+\text{]} = \text{[CO₃}^{2-}\text{]} + \text{[HCO₃}^-\text{]} + \text{[OH}^-\text{]} \]
**Explanation:**
These equations illustrate the charge balance in different chemical solutions.
- For HF solution, the hydrogen ions (\[\text{H}^+\]) balance with fluoride ions (\[\text{F}^-\]) and hydroxide ions (\[\text{OH}^-\]).
- In the solution of dimethylamine ((CH₃)₂NH), the positively charged ions (\[\text{(CH₃)₂NH₃}^+\]) are balanced with dimethylamine and hydroxide ions.
- For a solution saturated with silver carbonate (Ag₂CO₃), the silver ions and hydrogen ions together balance the carbonate or bicarbonate ions and hydroxide ions. The equation also accounts for potential equilibrium shifts that produce bicarbonate (\[\text{HCO₃}^-\]).](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fb2c2bfdd-c795-4c13-bc09-4b743040f0d9%2F99677442-d224-458f-9e3a-bd6d5ee5882a%2Fupvoo1i_processed.jpeg&w=3840&q=75)
Transcribed Image Text:**Charge-Balance Equations for Solutions:**
a. **0.15 M in HF**
- \[ \text{[H}^+\text{]} = \text{[F}^-\text{]} + \text{[OH}^-\text{]} \]
b. **0.16 M in (CH₃)₂NH**
- \[ \text{[CH₃)₂NH₃}^+\text{]} + \text{[OH}^-\text{]} = \text{[CH₃)₂NH]} \]
c. **Saturated with Ag₂CO₃**
- \[ 2\text{[Ag}^+\text{]} + \text{[H}^+\text{]} = \text{[CO₃}^{2-}\text{]} + \text{[HCO₃}^-\text{]} + \text{[OH}^-\text{]} \]
**Explanation:**
These equations illustrate the charge balance in different chemical solutions.
- For HF solution, the hydrogen ions (\[\text{H}^+\]) balance with fluoride ions (\[\text{F}^-\]) and hydroxide ions (\[\text{OH}^-\]).
- In the solution of dimethylamine ((CH₃)₂NH), the positively charged ions (\[\text{(CH₃)₂NH₃}^+\]) are balanced with dimethylamine and hydroxide ions.
- For a solution saturated with silver carbonate (Ag₂CO₃), the silver ions and hydrogen ions together balance the carbonate or bicarbonate ions and hydroxide ions. The equation also accounts for potential equilibrium shifts that produce bicarbonate (\[\text{HCO₃}^-\]).
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