Treatment of the bicyclic chloride A with lithium in tetrahydrofuran (THF) gave the monocyclic product B, C,H,Li. In deuterated THF, B exhibited a single proton NMR signal at 6.72 ppm and a single 13 C-NMR signal at about 110 ppm. Treatment of B with tetraethylammonium chloride gave a white solid in which N(C2H5)4 replaces Li. Draw a structure for the lithium derivative B. . A Li/THF (C2H5)4N CI CI CgHgLi CgH9N(C2H5)4 B Draw cations and anions in separate sketchers. . Separate structures with + signs from the drop-down menu.

Treatment of the bicyclic chloride A with lithium in tetrahydrofuran (THF) gave the monocyclic product B, C,H,Li. In deuterated THF, B exhibited a single proton NMR signal at 6.72 ppm and a single 13 C-NMR signal at about 110 ppm. Treatment of B with tetraethylammonium chloride gave a white solid in which N(C2H5)4 replaces Li. Draw a structure for the lithium derivative B. . A Li/THF (C2H5)4N CI CI CgHgLi CgH9N(C2H5)4 B Draw cations and anions in separate sketchers. . Separate structures with + signs from the drop-down menu.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Concept explainers

NMR Spectroscopy

NMR stands for Nuclear Magnetic Resonance in which the study of different molecules is done based on the interaction of radiofrequency electromagnetic radiations with the nuclei of molecules placed in a strong magnetic field. A precise study of spectra of visible light and all bands of electromagnetic radiation is called spectroscopy.

Question

Treatment of the bicyclic chloride A with lithium in tetrahydrofuran (THF) gave the monocyclic product B, C,H,Li. In
deuterated THF, B exhibited a single proton NMR signal at 6.72 ppm and a single 13 C-NMR signal at about 110 ppm.
Treatment of B with tetraethylammonium chloride gave a white solid in which N(C2H5)4 replaces Li. Draw a structure for
the lithium derivative B.
A
Li/THF
-CI
CgHgLi
(C2H5)4N CI
C9H9N(C2H5)4
B
Draw cations and anions in separate sketchers.
⚫ Separate structures with + signs from the drop-down menu.

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