Treatment of the bicyclic chloride A with lithium in tetrahydrofuran (THF) gave the monocyclic product B, C,H,Li. In deuterated THF, B exhibited a single proton NMR signal at 6.72 ppm and a single 13C-NMR signal at about 110 ppm. Treatment of B with tetraethylammonium chloride gave a white solid in which N(C₂H5)4 replaces Li. Draw a structure for the lithium derivative B. A Li/THF CgHgLi B • Draw cations and anions in separate sketchers. • Separate structures with + signs from the drop-down menu. (C₂H5)4N* CI CgHgN(C₂H5)4
Treatment of the bicyclic chloride A with lithium in tetrahydrofuran (THF) gave the monocyclic product B, C,H,Li. In deuterated THF, B exhibited a single proton NMR signal at 6.72 ppm and a single 13C-NMR signal at about 110 ppm. Treatment of B with tetraethylammonium chloride gave a white solid in which N(C₂H5)4 replaces Li. Draw a structure for the lithium derivative B. A Li/THF CgHgLi B • Draw cations and anions in separate sketchers. • Separate structures with + signs from the drop-down menu. (C₂H5)4N* CI CgHgN(C₂H5)4
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:Treatment of the bicyclic chloride A with lithium in tetrahydrofuran (THF) gave the monocyclic product B, C,HgLi. In
deuterated THF, B exhibited a single proton NMR signal at 6.72 ppm and a single 13C-NMR signal at about 110 ppm.
Treatment of B with tetraethylammonium chloride gave a white solid in which N(C₂H5)4 replaces Li. Draw a structure for
the lithium derivative B.
A
Li/THF
9985
CgHgLi
B
• Draw cations and anions in separate sketchers.
• Separate structures with + signs from the drop-down menu.
(C₂H5)4N* CI
CgHgN(C₂H5)4
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