Train track rails are joined using an exothermic welding process. A mixture of iron (III) oxide (Fe₂O3), and aluminium metal (Al) is employed and the process is described by the following chemical reaction: Fe₂O3(s) + 2Al(s) →→→ Al₂O3(s) + 2Fe(s) AfH (kJ mol-1) c(g-¹ K-¹) 0 0.451 Fe(s) Fe₂O3(s) -822.3 0.651 Al(s) 0 0.900 Al₂O3(s) -1669.8 0.753 Calculate the heat released by this process.

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Chapter1: Chemical Foundations
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Train track rails are joined using an exothermic welding process. A
mixture of iron (III) oxide (Fe2O3), and aluminium metal (Al) is employed
and the process is described by the following chemical reaction:
Fe₂O3(s) + 2Al(s) → Al₂O3(s) + 2Fe(s)
AH (kJ mol-1)
c(g-¹ K-1)
0
0.451
Fe(s)
Fe₂O3(s)
-822.3
0.651
0
0.900
Al(s)
Al2O3(s)
-1669.8
0.753
a) Calculate the heat released by this process.
b) Assuming the reaction goes to completion and that all the heat goes
into the final mixture, calculate the final temperature of the products
before heat has flowed into the surroundings. Comment on whether the
calculated temperature is reasonable.
c) Calculate the entropy change for the surroundings once the system
and surroundings have equilibrated to the surrounding temperature of
25 °C.
Transcribed Image Text:Train track rails are joined using an exothermic welding process. A mixture of iron (III) oxide (Fe2O3), and aluminium metal (Al) is employed and the process is described by the following chemical reaction: Fe₂O3(s) + 2Al(s) → Al₂O3(s) + 2Fe(s) AH (kJ mol-1) c(g-¹ K-1) 0 0.451 Fe(s) Fe₂O3(s) -822.3 0.651 0 0.900 Al(s) Al2O3(s) -1669.8 0.753 a) Calculate the heat released by this process. b) Assuming the reaction goes to completion and that all the heat goes into the final mixture, calculate the final temperature of the products before heat has flowed into the surroundings. Comment on whether the calculated temperature is reasonable. c) Calculate the entropy change for the surroundings once the system and surroundings have equilibrated to the surrounding temperature of 25 °C.
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