TR 04 1. Determine A and Ea from the following data 350 k/M-1.s-1 7.9.10^6 3.0.10^7 7.9.10^7 1.7.10^8 3.2.10 8 T/K 300 400 450 500 (Atkins, 808)

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TR 04
1. Determine A and Ea from the following data
300
T/K
350
400
450
500
k/M-1.s-1 7.9.10^6 3.0.10^7 7.9.10^7 1.7.10^8 3.2.10^8
(Atkins, 808)
2. The rate of the second order decomposition of acetaldehyde was measured over the
temperature range 700 - 1000 K, and rate constants are reported below. Find Ea and A
810
840 910
20.0
T/K
700
730
760
790
1000
k
0.011 0.035 0.105 0.343 0.789 2.17
145
(Atkins, 808)
3. Some values of the rate constant for the alkaline hydrolysis of ethyl iodide over the
temperature range 200C-800C are as follows
0.335 1.41 3.06 8.17
40
K 10^3
0.100
21.1 50.1
T/C
20
30
50
60
70
80
Calculate the activation energy of the reaction (Ea) and pre-exponential factor (A).
(Avery, 50)
Transcribed Image Text:TR 04 1. Determine A and Ea from the following data 300 T/K 350 400 450 500 k/M-1.s-1 7.9.10^6 3.0.10^7 7.9.10^7 1.7.10^8 3.2.10^8 (Atkins, 808) 2. The rate of the second order decomposition of acetaldehyde was measured over the temperature range 700 - 1000 K, and rate constants are reported below. Find Ea and A 810 840 910 20.0 T/K 700 730 760 790 1000 k 0.011 0.035 0.105 0.343 0.789 2.17 145 (Atkins, 808) 3. Some values of the rate constant for the alkaline hydrolysis of ethyl iodide over the temperature range 200C-800C are as follows 0.335 1.41 3.06 8.17 40 K 10^3 0.100 21.1 50.1 T/C 20 30 50 60 70 80 Calculate the activation energy of the reaction (Ea) and pre-exponential factor (A). (Avery, 50)
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