Total number of stereoisomers possible for the following compounds is HINT: How many possible stereoisomers? How do we know how many stereoisomers are possible for a given structure? There is actually a straightforward way to figure this out. All we need to do i count the number of chiral centers and stereogenic alkene groups, the use this following rule: number of stereoisomeric forms = 2" ... where n = the number of chiral centers plus the number of stereogenic alkene groups a. 4 Consider for example a molecule with two chiral centers and one stereogenic alkene. By the rule stated above, we know right away that there must be eigh possible stereoisomers. terminal alkene stereogenic alkene OH b. 2 OH C. 8 d. 3 OH HO chiral center OH = 8 nonstereogenic alkenes (cannot be labelled E or Z)

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter3: Organic Compounds: Alkanes And Their Stereochemistry
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Total number of stereoisomers possible for the following
compounds is
HINT:
a. 4
How many possible stereoisomers?
How do we know how many stereoisomers are possible for a given structure? There is actually a straightforward way to figure this out. All we need to do is
count the number of chiral centers and stereogenic alkene groups, the use this following rule:
number of stereoisomeric forms = 2"
... where n = the number of chiral centers plus the number of stereogenic alkene groups
b. 2
Consider for example a molecule with two chiral centers and one stereogenic alkene. By the rule stated above, we know right away that there must be eight
possible stereoisomers.
terminal alkene
OH
stereogenic alkene
C. 8
OH
d. 3
OH
chiral center
HO
OH
3
2 = 8
T
nonstereogenic alkenes (cannot be labelled E or Z)
←
Transcribed Image Text:Total number of stereoisomers possible for the following compounds is HINT: a. 4 How many possible stereoisomers? How do we know how many stereoisomers are possible for a given structure? There is actually a straightforward way to figure this out. All we need to do is count the number of chiral centers and stereogenic alkene groups, the use this following rule: number of stereoisomeric forms = 2" ... where n = the number of chiral centers plus the number of stereogenic alkene groups b. 2 Consider for example a molecule with two chiral centers and one stereogenic alkene. By the rule stated above, we know right away that there must be eight possible stereoisomers. terminal alkene OH stereogenic alkene C. 8 OH d. 3 OH chiral center HO OH 3 2 = 8 T nonstereogenic alkenes (cannot be labelled E or Z) ←
Predict the 1H shifts of the protons on the labeled carbons of the following chemical structure:
OH
NH₂
a
N
H(1) 5.40, H(2)=5.46
b. H(1)=5.46, H(2)=5.40
c. H(1) 6.64, H(2)=6.60
d. H(1)=5.54, H(2)=5.58
e. H(1) 6.40, H(2)=6.44
Transcribed Image Text:Predict the 1H shifts of the protons on the labeled carbons of the following chemical structure: OH NH₂ a N H(1) 5.40, H(2)=5.46 b. H(1)=5.46, H(2)=5.40 c. H(1) 6.64, H(2)=6.60 d. H(1)=5.54, H(2)=5.58 e. H(1) 6.40, H(2)=6.44
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