Toluene vapors at 1.013 bar, 150°C, are cooled under constant pressure to a final temperature of 22°C. (a) Determine the amount of heat that must be removed (b) How much heat must be removed if the final state is a vapor-liquid mixture that contains 60% vapor by mass. Assume that Cp for vapor phase is a function of temperature, and for liquid toluene Cp is constant (= 155.96 J/(mol K)). The boiling temperature of toluene at 1.013 bar is 110.6°C, and standard heat of vaporization for toluene 38060 J/mol.

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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Chapter1: Introduction
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Toluene vapors at 1.013 bar, 150°C, are cooled under constant pressure
to a final temperature of 22°C.


(a) Determine the amount of heat that must be removed
(b) How much heat must be removed if the final state is a vapor-liquid mixture that contains
60% vapor by mass.


Assume that Cp for vapor phase is a function of temperature, and for liquid toluene Cp is constant (= 155.96 J/(mol K)). The boiling temperature of toluene at 1.013 bar is 110.6°C, and standard heat of vaporization for toluene 38060 J/mol.

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