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to nitrogen dioxide and chlorine, according to the 2 NO₂Cl 2 NO2 + Cl2 The experimental rate law for this reaction is Rate = k [NO₂CI] Which, if any, of the following mechanisms are consistent with the observed rate law? More than one answer is possible. Write the overall reaction and rate law for each mechanism. a) NO₂CINO₂ + Cl (slow) CI+NO₂CI NO2 + Cl₂ (fast) 1) Nitryl chloride decomposes following reaction: b) 2 NO₂CI k2 N₂O4 c) 2 NO₂CI 2 NO₂ (slow) N₂O + CIO₂ N₂O4 N2O4 + Cl2 (fast equilibrium) k3 CIO2 + N₂O + CIO (fast equilibrium) + NOCI (fast equilibrium) NOCI+CIO → NO2 + Cl2 (slow)

to nitrogen dioxide and chlorine, according to the 2 NO₂Cl 2 NO2 + Cl2 The experimental rate law for this reaction is Rate = k [NO₂CI] Which, if any, of the following mechanisms are consistent with the observed rate law? More than one answer is possible. Write the overall reaction and rate law for each mechanism. a) NO₂CINO₂ + Cl (slow) CI+NO₂CI NO2 + Cl₂ (fast) 1) Nitryl chloride decomposes following reaction: b) 2 NO₂CI k2 N₂O4 c) 2 NO₂CI 2 NO₂ (slow) N₂O + CIO₂ N₂O4 N2O4 + Cl2 (fast equilibrium) k3 CIO2 + N₂O + CIO (fast equilibrium) + NOCI (fast equilibrium) NOCI+CIO → NO2 + Cl2 (slow)

Chemistry
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Chem 102 Chapter 15 Workshop, Part 2: Kinetics 1) Nitryl chloride decomposes to nitrogen dioxide and chlorine, according to the following reaction: 2 NO₂CI → 2 NO₂ + Cl₂ The experimental rate law for this reaction is Rate = k [NO₂CI] Which, if any, of the following mechanisms are consistent with the observed rate law? More than one answer is possible. Write the overall reaction and rate law for each mechanism. a) NO₂CINO₂ + Cl (slow) k2 CI + NO₂CI NO₂ + Cl₂ (fast) b) 2 NO₂Cl k2 N₂O4 c) 2 NO₂CI N₂O4 + Cl₂ (fast equilibrium) 2 NO₂ (slow) N₂O + CIO₂ CIO2 + N₂O + CIO (fast equilibrium) NO₂ + NOCI (fast equilibrium) Dr. Harvey k3 NOCI+ CIO NO₂ + Cl₂ (slow) 2) Given the following reaction mechanism,
Transcribed Image Text:Chem 102 Chapter 15 Workshop, Part 2: Kinetics 1) Nitryl chloride decomposes to nitrogen dioxide and chlorine, according to the following reaction: 2 NO₂CI → 2 NO₂ + Cl₂ The experimental rate law for this reaction is Rate = k [NO₂CI] Which, if any, of the following mechanisms are consistent with the observed rate law? More than one answer is possible. Write the overall reaction and rate law for each mechanism. a) NO₂CINO₂ + Cl (slow) k2 CI + NO₂CI NO₂ + Cl₂ (fast) b) 2 NO₂Cl k2 N₂O4 c) 2 NO₂CI N₂O4 + Cl₂ (fast equilibrium) 2 NO₂ (slow) N₂O + CIO₂ CIO2 + N₂O + CIO (fast equilibrium) NO₂ + NOCI (fast equilibrium) Dr. Harvey k3 NOCI+ CIO NO₂ + Cl₂ (slow) 2) Given the following reaction mechanism,
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