to nitrogen dioxide and chlorine, according to the 2 NO₂Cl 2 NO2 + Cl2 The experimental rate law for this reaction is Rate = k [NO₂CI] Which, if any, of the following mechanisms are consistent with the observed rate law? More than one answer is possible. Write the overall reaction and rate law for each mechanism. a) NO₂CINO₂ + Cl (slow) CI+NO₂CI NO2 + Cl₂ (fast) 1) Nitryl chloride decomposes following reaction: b) 2 NO₂CI k2 N₂O4 c) 2 NO₂CI 2 NO₂ (slow) N₂O + CIO₂ N₂O4 N2O4 + Cl2 (fast equilibrium) k3 CIO2 + N₂O + CIO (fast equilibrium) + NOCI (fast equilibrium) NOCI+CIO → NO2 + Cl2 (slow)
to nitrogen dioxide and chlorine, according to the 2 NO₂Cl 2 NO2 + Cl2 The experimental rate law for this reaction is Rate = k [NO₂CI] Which, if any, of the following mechanisms are consistent with the observed rate law? More than one answer is possible. Write the overall reaction and rate law for each mechanism. a) NO₂CINO₂ + Cl (slow) CI+NO₂CI NO2 + Cl₂ (fast) 1) Nitryl chloride decomposes following reaction: b) 2 NO₂CI k2 N₂O4 c) 2 NO₂CI 2 NO₂ (slow) N₂O + CIO₂ N₂O4 N2O4 + Cl2 (fast equilibrium) k3 CIO2 + N₂O + CIO (fast equilibrium) + NOCI (fast equilibrium) NOCI+CIO → NO2 + Cl2 (slow)
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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plz help me solve question 1
![Chem 102
Chapter 15 Workshop, Part 2: Kinetics
1) Nitryl chloride decomposes to nitrogen dioxide and chlorine, according to the
following reaction:
2 NO₂CI → 2 NO₂ + Cl₂
The experimental rate law for this reaction is Rate = k [NO₂CI]
Which, if any, of the following mechanisms are consistent with the observed rate law?
More than one answer is possible.
Write the overall reaction and rate law for each mechanism.
a) NO₂CINO₂ + Cl (slow)
k2
CI + NO₂CI NO₂ + Cl₂ (fast)
b) 2 NO₂Cl
k2
N₂O4
c) 2 NO₂CI
N₂O4 + Cl₂ (fast equilibrium)
2 NO₂ (slow)
N₂O + CIO₂
CIO2 + N₂O + CIO (fast equilibrium)
NO₂ + NOCI (fast equilibrium)
Dr. Harvey
k3
NOCI+ CIO NO₂ + Cl₂ (slow)
2) Given the following reaction mechanism,](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fd38dc3ae-53e5-4279-afed-9e69fa663b8c%2F04404afc-3353-4b10-b3e5-57b67e3290ae%2Fdnbbsm_processed.png&w=3840&q=75)
Transcribed Image Text:Chem 102
Chapter 15 Workshop, Part 2: Kinetics
1) Nitryl chloride decomposes to nitrogen dioxide and chlorine, according to the
following reaction:
2 NO₂CI → 2 NO₂ + Cl₂
The experimental rate law for this reaction is Rate = k [NO₂CI]
Which, if any, of the following mechanisms are consistent with the observed rate law?
More than one answer is possible.
Write the overall reaction and rate law for each mechanism.
a) NO₂CINO₂ + Cl (slow)
k2
CI + NO₂CI NO₂ + Cl₂ (fast)
b) 2 NO₂Cl
k2
N₂O4
c) 2 NO₂CI
N₂O4 + Cl₂ (fast equilibrium)
2 NO₂ (slow)
N₂O + CIO₂
CIO2 + N₂O + CIO (fast equilibrium)
NO₂ + NOCI (fast equilibrium)
Dr. Harvey
k3
NOCI+ CIO NO₂ + Cl₂ (slow)
2) Given the following reaction mechanism,
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