This question relates to the energies of electrons in multielectron atoms. a) Can energies of electrons in multielectron atoms be determined exactly? Why or why not? b) Briefly describe the main idea of the variational principle and how it is used in the variational method.

World of Chemistry, 3rd edition
3rd Edition
ISBN:9781133109655
Author:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCoste
Chapter11: Modern Atomic Theory
Section: Chapter Questions
Problem 23A
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This question relates to the energies of electrons in multielectron atoms.

a) Can energies of electrons in multielectron atoms be determined exactly? Why or why not?

b) Briefly describe the main idea of the variational principle and how it is used in the variational method.

 

 

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