There is a solution containing two metal cations. The goal is to separate them by slowly and carefully adding a solution of an anion, until one mental cation precipitates as a compound with that anion, leaving the other metal cation still in solution. M+ is Ag+, M2+ is Ca2+, anion is SO4 2-, first Ksp is 1.2 x 10-5, second Ksp is 6.1 x 10-5, and the starting concentrations of M+ is 1.50 x 10-2 M and M2+ is 3.50 x 10-2M. Using these values, predict which metal will precipitate first and what concentration of anion the precipitation will begin.

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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There is a solution containing two metal cations. The goal is to separate them by slowly and carefully adding a solution of an anion, until one mental cation precipitates as a compound with that anion, leaving the other metal cation still in solution. M+ is Ag+, M2+ is Ca2+, anion is SO4 2-, first Ksp is 1.2 x 10-5, second Ksp is 6.1 x 10-5, and the starting concentrations of M+ is 1.50 x 10-2 M and M2+ is 3.50 x 10-2M. Using these values, predict which metal will precipitate first and what concentration of anion the precipitation will begin.
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