The water-gas reaction is a source of hydrogen. Passing steam over hot carbon produces a mixture of carbon monoxide and hydrogen. H2O(g)+C(s) -------------> CO(g)+H2(g) <------------- The value of Kc for the reaction at 1000.0°C is 3.00 × 10–2. Calculate the equilibrium partial pressure of H2O given that PH2O = 0.442 atm and PCO = 5.000 atm at the start of the reaction. Assume that the carbon is in excess. _________ atm Calculate the equilibrium partial pressure of CO. _________ atm Calculate the equilibrium partial pressure of H2. _________ atm Determine the equilibrium partial pressure of H2O after CO and H2 at 0.0720 atm are added to the equilibrium mixture described above. _________ atm Determine the equilibrium partial pressure of CO after the addition described above. _________ atm Determine the equilibrium partial pressure of H2 after the addition described above. ________ atm
Ideal and Real Gases
Ideal gases obey conditions of the general gas laws under all states of pressure and temperature. Ideal gases are also named perfect gases. The attributes of ideal gases are as follows,
Gas Laws
Gas laws describe the ways in which volume, temperature, pressure, and other conditions correlate when matter is in a gaseous state. The very first observations about the physical properties of gases was made by Robert Boyle in 1662. Later discoveries were made by Charles, Gay-Lussac, Avogadro, and others. Eventually, these observations were combined to produce the ideal gas law.
Gaseous State
It is well known that matter exists in different forms in our surroundings. There are five known states of matter, such as solids, gases, liquids, plasma and Bose-Einstein condensate. The last two are known newly in the recent days. Thus, the detailed forms of matter studied are solids, gases and liquids. The best example of a substance that is present in different states is water. It is solid ice, gaseous vapor or steam and liquid water depending on the temperature and pressure conditions. This is due to the difference in the intermolecular forces and distances. The occurrence of three different phases is due to the difference in the two major forces, the force which tends to tightly hold molecules i.e., forces of attraction and the disruptive forces obtained from the thermal energy of molecules.
H2O(g)+C(s) -------------> CO(g)+H2(g)
<-------------
The value of Kc for the reaction at 1000.0°C is 3.00 × 10–2.
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