The vapor pressure of pure toluene (C6H5CH3, MW = 92.14 g/mol) at T = 100.0 °C is pT° = 557.0 torr. What is the vapor pressure of a solution containing 20.00 g of naphthalene (C10H8, MW = 128.17 g/mol), a nonvolatile solute, and 240.0 g of toluene, at T = 100.0 °C?

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The vapor pressure of pure toluene (C6H5CH3, MW = 92.14 g/mol) at T = 100.0 °C is pT° = 557.0 torr.  What is the vapor pressure of a solution containing 20.00 g of naphthalene (C10H8, MW = 128.17 g/mol), a nonvolatile solute, and 240.0 g of toluene, at T = 100.0 °C?

 

Expert Solution
Step 1

The Raoult's for non volatile solute can be expressed as,

                             Chemistry homework question answer, step 1, image 1

Where, P0 is the vapour pressure of the solvent

            Psol is the vapour pressure of the solution

             x2 is the mole fraction of the solute

             n1 is the number of moles of solvent

             n2 is the number of moles of solute

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