The vapor pressure of ethanol is 54.68 mm Hg at 25 °C. A nonvolatile, nonelectrolyte that dissolves in ethanol is saccharin Calculate the vapor pressure of the solution at 25 °C when 13.39 grams of saccharin, C-H5NO3S (183.2 g/mol), are dissolved in 204.9 grams of ethanol. ethanol = CH3CH2OH = 46.07 g/mol. VP(solution) = mm Hg
The vapor pressure of ethanol is 54.68 mm Hg at 25 °C. A nonvolatile, nonelectrolyte that dissolves in ethanol is saccharin Calculate the vapor pressure of the solution at 25 °C when 13.39 grams of saccharin, C-H5NO3S (183.2 g/mol), are dissolved in 204.9 grams of ethanol. ethanol = CH3CH2OH = 46.07 g/mol. VP(solution) = mm Hg
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
Related questions
Question
100%
![### Calculating Vapor Pressure of a Solution
**Problem Statement:**
The vapor pressure of **ethanol** is 54.68 mm Hg at 25 °C. A nonvolatile, nonelectrolyte that dissolves in ethanol is **saccharin**.
Calculate the vapor pressure of the solution at 25 °C when 13.39 grams of saccharin, \( C_7H_5NO_3S \) (183.2 g/mol), are dissolved in 204.9 grams of ethanol.
**Given:**
- Ethanol = \( C_2H_5OH \) = 46.07 g/mol
- Vapor Pressure of ethanol = 54.68 mm Hg
- Mass of saccharin = 13.39 g
- Mass of ethanol = 204.9 g
**Solution:**
To find the vapor pressure of the solution, use Raoult's Law:
\[
\text{VP(solution)} = \text{VP(pure solvent)} \times \text{mole fraction of solvent}
\]
### Steps:
1. **Calculate Moles:**
- Moles of saccharin:
\[
\left(\frac{13.39 \text{ g}}{183.2 \text{ g/mol}}\right) = 0.0731 \text{ moles}
\]
- Moles of ethanol:
\[
\left(\frac{204.9 \text{ g}}{46.07 \text{ g/mol}}\right) = 4.448 \text{ moles}
\]
2. **Calculate Mole Fraction of Ethanol:**
- Total moles = 0.0731 + 4.448 = 4.521 moles
- Mole fraction of ethanol:
\[
\left(\frac{4.448}{4.521}\right) = 0.9839
\]
3. **Calculate Vapor Pressure of the Solution:**
- Using Raoult's Law:
\[
\text{VP(solution)} = 54.68 \times 0.9839 = 53.80 \text{ mm Hg}
\]
**Conclusion:**
The vapor pressure of the solution containing saccharin and ethanol at 25 °C is 53.80 mm Hg.
**Interactive Components:](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fd625bb90-bef1-43a1-8a4c-22731e64d06f%2F7d750988-cf63-4210-b046-1b1002465422%2Fy598idc_processed.jpeg&w=3840&q=75)
Transcribed Image Text:### Calculating Vapor Pressure of a Solution
**Problem Statement:**
The vapor pressure of **ethanol** is 54.68 mm Hg at 25 °C. A nonvolatile, nonelectrolyte that dissolves in ethanol is **saccharin**.
Calculate the vapor pressure of the solution at 25 °C when 13.39 grams of saccharin, \( C_7H_5NO_3S \) (183.2 g/mol), are dissolved in 204.9 grams of ethanol.
**Given:**
- Ethanol = \( C_2H_5OH \) = 46.07 g/mol
- Vapor Pressure of ethanol = 54.68 mm Hg
- Mass of saccharin = 13.39 g
- Mass of ethanol = 204.9 g
**Solution:**
To find the vapor pressure of the solution, use Raoult's Law:
\[
\text{VP(solution)} = \text{VP(pure solvent)} \times \text{mole fraction of solvent}
\]
### Steps:
1. **Calculate Moles:**
- Moles of saccharin:
\[
\left(\frac{13.39 \text{ g}}{183.2 \text{ g/mol}}\right) = 0.0731 \text{ moles}
\]
- Moles of ethanol:
\[
\left(\frac{204.9 \text{ g}}{46.07 \text{ g/mol}}\right) = 4.448 \text{ moles}
\]
2. **Calculate Mole Fraction of Ethanol:**
- Total moles = 0.0731 + 4.448 = 4.521 moles
- Mole fraction of ethanol:
\[
\left(\frac{4.448}{4.521}\right) = 0.9839
\]
3. **Calculate Vapor Pressure of the Solution:**
- Using Raoult's Law:
\[
\text{VP(solution)} = 54.68 \times 0.9839 = 53.80 \text{ mm Hg}
\]
**Conclusion:**
The vapor pressure of the solution containing saccharin and ethanol at 25 °C is 53.80 mm Hg.
**Interactive Components:
![**Problem Statement:**
The vapor pressure of ethanol is 54.68 mm Hg at 25°C.
**Question:**
How many grams of estrogen (estradiol), C₁₈H₂₄O₂, a nonvolatile, nonelectrolyte (MW = 272.4 g/mol), must be added to 245.3 grams of ethanol to reduce the vapor pressure to 53.74 mm Hg?
**Given Data:**
- Ethanol formula: CH₃CH₂OH
- Molar mass of ethanol: 46.07 g/mol
**Calculation Required:**
\[\_\_\_\_\_\_\_\_\_\] g of estrogen
**Options for Submission:**
- Submit Answer
- Retry Entire Group
- 9 more group attempts remaining
**Technical Support:**
Cengage Learning | Cengage Technical Support
(Note: Below the problem, navigation options such as "Previous" and "Next" are available for moving through the questions.)](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fd625bb90-bef1-43a1-8a4c-22731e64d06f%2F7d750988-cf63-4210-b046-1b1002465422%2Fc5ujfbb_processed.jpeg&w=3840&q=75)
Transcribed Image Text:**Problem Statement:**
The vapor pressure of ethanol is 54.68 mm Hg at 25°C.
**Question:**
How many grams of estrogen (estradiol), C₁₈H₂₄O₂, a nonvolatile, nonelectrolyte (MW = 272.4 g/mol), must be added to 245.3 grams of ethanol to reduce the vapor pressure to 53.74 mm Hg?
**Given Data:**
- Ethanol formula: CH₃CH₂OH
- Molar mass of ethanol: 46.07 g/mol
**Calculation Required:**
\[\_\_\_\_\_\_\_\_\_\] g of estrogen
**Options for Submission:**
- Submit Answer
- Retry Entire Group
- 9 more group attempts remaining
**Technical Support:**
Cengage Learning | Cengage Technical Support
(Note: Below the problem, navigation options such as "Previous" and "Next" are available for moving through the questions.)
Expert Solution
![](/static/compass_v2/shared-icons/check-mark.png)
This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
This is a popular solution!
Trending now
This is a popular solution!
Step by step
Solved in 2 steps
![Blurred answer](/static/compass_v2/solution-images/blurred-answer.jpg)
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Recommended textbooks for you
![Chemistry](https://www.bartleby.com/isbn_cover_images/9781305957404/9781305957404_smallCoverImage.gif)
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
![Chemistry](https://www.bartleby.com/isbn_cover_images/9781259911156/9781259911156_smallCoverImage.gif)
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
![Principles of Instrumental Analysis](https://www.bartleby.com/isbn_cover_images/9781305577213/9781305577213_smallCoverImage.gif)
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
![Chemistry](https://www.bartleby.com/isbn_cover_images/9781305957404/9781305957404_smallCoverImage.gif)
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
![Chemistry](https://www.bartleby.com/isbn_cover_images/9781259911156/9781259911156_smallCoverImage.gif)
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
![Principles of Instrumental Analysis](https://www.bartleby.com/isbn_cover_images/9781305577213/9781305577213_smallCoverImage.gif)
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
![Organic Chemistry](https://www.bartleby.com/isbn_cover_images/9780078021558/9780078021558_smallCoverImage.gif)
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
![Chemistry: Principles and Reactions](https://www.bartleby.com/isbn_cover_images/9781305079373/9781305079373_smallCoverImage.gif)
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
![Elementary Principles of Chemical Processes, Bind…](https://www.bartleby.com/isbn_cover_images/9781118431221/9781118431221_smallCoverImage.gif)
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY