The total concentration of Ca²+ and Mg²+ in a sample of hard water was determined by titrating a 0.100-L sample of the water with a solution of EDTA. The EDTA chelates the two cations: Mg+ + [EDTA]+ Ca2+ + [EDTA]+ [Mg(EDTA)]²- [Ca(EDTA)]?- It requires 31.5 ml. of 0.0104 M[EDTA]* solution to reach the end point in the titration. A second 0.100-L sample was then treated with sulfate ion to precipitate Ca?+ as calcium sulfate. The Mg2+ was then titrated with 18.7 mL of 0.0104 M [EDTA]*. Calculate the concentrations of Mg²+ and Ca2 in the hard water in mg/L.
The total concentration of Ca²+ and Mg²+ in a sample of hard water was determined by titrating a 0.100-L sample of the water with a solution of EDTA. The EDTA chelates the two cations: Mg+ + [EDTA]+ Ca2+ + [EDTA]+ [Mg(EDTA)]²- [Ca(EDTA)]?- It requires 31.5 ml. of 0.0104 M[EDTA]* solution to reach the end point in the titration. A second 0.100-L sample was then treated with sulfate ion to precipitate Ca?+ as calcium sulfate. The Mg2+ was then titrated with 18.7 mL of 0.0104 M [EDTA]*. Calculate the concentrations of Mg²+ and Ca2 in the hard water in mg/L.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![The total concentration of Ca²+ and Mg²+ in a sample of
hard water was determined by titrating a 0.100-L sample of
the water with a solution of EDTA. The EDTA chelates
the two cations:
Mg+ + [EDTA]+
Ca2+ + [EDTA]+
[Mg(EDTA)]²-
[Ca(EDTA)]?-
It requires 31.5 ml. of 0.0104 M[EDTA]* solution to reach
the end point in the titration. A second 0.100-L sample was
then treated with sulfate ion to precipitate Ca?+ as calcium
sulfate. The Mg2+ was then titrated with 18.7 mL of 0.0104
M [EDTA]*. Calculate the concentrations of Mg²+ and
Ca2 in the hard water in mg/L.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F78de058a-94df-4fa5-94dc-4100556a8ae0%2F664bebe3-1a6d-4611-bf57-ea0132fab680%2F8j7s3r.png&w=3840&q=75)
Transcribed Image Text:The total concentration of Ca²+ and Mg²+ in a sample of
hard water was determined by titrating a 0.100-L sample of
the water with a solution of EDTA. The EDTA chelates
the two cations:
Mg+ + [EDTA]+
Ca2+ + [EDTA]+
[Mg(EDTA)]²-
[Ca(EDTA)]?-
It requires 31.5 ml. of 0.0104 M[EDTA]* solution to reach
the end point in the titration. A second 0.100-L sample was
then treated with sulfate ion to precipitate Ca?+ as calcium
sulfate. The Mg2+ was then titrated with 18.7 mL of 0.0104
M [EDTA]*. Calculate the concentrations of Mg²+ and
Ca2 in the hard water in mg/L.
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