The thickness of the chromium plate on an auto fender is determined by dissolving a 30.0-cm2 section in acid and oxidizing Cr3+ to Cr2O7 2-with peroxydisulfate. After removing excess peroxydisulfate by boiling, 500.0 mg of Fe(NH4 )2 (SO4 )2•6H2O is added, reducing the Cr2O7 2- to Cr3+ . The excess Fe2+ is back titrated, requiring 18.29 mL of 0.00389 M K2Cr2O7 to reach the end point. Determine the average thickness of the chromium plate given that the density of Cr is 7.20 g/cm3

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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The thickness of the chromium plate on an auto fender is
determined by dissolving a 30.0-cm2
section in acid and
oxidizing Cr3+ to Cr2O7
2-with peroxydisulfate. After removing
excess peroxydisulfate by boiling, 500.0 mg of
Fe(NH4
)2
(SO4
)2•6H2O is added, reducing the Cr2O7
2-
to Cr3+
.
The excess Fe2+ is back titrated, requiring 18.29 mL of 0.00389
M K2Cr2O7 to reach the end point. Determine the average
thickness of the chromium plate given that the density of Cr is
7.20 g/cm3
. Note: thickness = volume /area

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