The substance chlorine monoxide, ClO(g), is important inatmospheric processes that lead to depletion of the ozonelayer. The ClO molecule has an experimental dipole momentof 1.24 D, and the Cl¬O bond length is 1.60 Å. (a)Determine the magnitude of the charges on the Cl and Oatoms in units of the electronic charge, e. (b) Based on theelectronegativities of the elements, which atom would youexpect to have a partial negative charge in the ClO molecule?(c) Using formal charges as a guide, propose the dominantLewis structure for the molecule. (d) The anion ClOexists.What is the formal charge on the Cl for the best Lewisstructure for ClO-?

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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The substance chlorine monoxide, ClO(g), is important in
atmospheric processes that lead to depletion of the ozone
layer. The ClO molecule has an experimental dipole moment
of 1.24 D, and the Cl¬O bond length is 1.60 Å. (a)
Determine the magnitude of the charges on the Cl and O
atoms in units of the electronic charge, e. (b) Based on the
electronegativities of the elements, which atom would you
expect to have a partial negative charge in the ClO molecule?
(c) Using formal charges as a guide, propose the dominant
Lewis structure for the molecule. (d) The anion ClOexists.
What is the formal charge on the Cl for the best Lewis
structure for ClO-?

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