The standard free energies of formation (AG) of the three isomers of pentane (see p. 365) in the gas phase are: n-pentane: -8.37 kJ/mol; 2-methylbutane: -14.8 kJ/mol; 2,2-dimethylpropane: -15.2 kJ/mol. (a) Determine the mole percent of these molecules in an equilibrium mixture at 25°C. (b) How does the stability of these molecules depend on the extent of branching?

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18.93 The standard free energies of formation (AG) of the
three isomers of pentane (see p. 365) in the gas phase
are: n-pentane: -8.37 kJ/mol; 2-methylbutane:
-14.8 kJ/mol; 2,2-dimethylpropane: -15.2 kJ/mol.
(a) Determine the mole percent of these molecules in
an equilibrium mixture at 25°C. (b) How does the
stability of these molecules depend on the extent of
branching?
Transcribed Image Text:18.93 The standard free energies of formation (AG) of the three isomers of pentane (see p. 365) in the gas phase are: n-pentane: -8.37 kJ/mol; 2-methylbutane: -14.8 kJ/mol; 2,2-dimethylpropane: -15.2 kJ/mol. (a) Determine the mole percent of these molecules in an equilibrium mixture at 25°C. (b) How does the stability of these molecules depend on the extent of branching?
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