The specific rotation of vitamin B7 in water (at 22°C) is +92. A chemist prepared a mixture of vitamin B7 and its enantiomer, and this mixture had a specific rotation of +12. Calculate the % ee of this mixture. % ee = i

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
**Calculating Enantiomeric Excess (% ee)**

**Question:**

The specific rotation of vitamin B₇ in water (at 22°C) is +92. A chemist prepared a mixture of vitamin B₇ and its enantiomer, and this mixture had a specific rotation of +12. Calculate the % ee of this mixture.

**Answer:**

To calculate the enantiomeric excess (% ee) of the mixture, use the following formula:

% ee = \(\left( \frac{\text{observed specific rotation}}{\text{specific rotation of pure enantiomer}} \right) \times 100 \)

Given:
- Specific rotation of pure vitamin B₇ = +92
- Specific rotation of the mixture = +12

Substitute the values into the formula:

% ee = \(\left( \frac{+12}{+92} \right) \times 100 \)
% ee = 13.04

Thus, the enantiomeric excess (% ee) of the mixture is 13.04%.

**Interactive Element:**

% ee = [   13.04   ]   %

Note: The box above is an input field where users can enter their answer and check if it's correct.
Transcribed Image Text:**Calculating Enantiomeric Excess (% ee)** **Question:** The specific rotation of vitamin B₇ in water (at 22°C) is +92. A chemist prepared a mixture of vitamin B₇ and its enantiomer, and this mixture had a specific rotation of +12. Calculate the % ee of this mixture. **Answer:** To calculate the enantiomeric excess (% ee) of the mixture, use the following formula: % ee = \(\left( \frac{\text{observed specific rotation}}{\text{specific rotation of pure enantiomer}} \right) \times 100 \) Given: - Specific rotation of pure vitamin B₇ = +92 - Specific rotation of the mixture = +12 Substitute the values into the formula: % ee = \(\left( \frac{+12}{+92} \right) \times 100 \) % ee = 13.04 Thus, the enantiomeric excess (% ee) of the mixture is 13.04%. **Interactive Element:** % ee = [ 13.04 ] % Note: The box above is an input field where users can enter their answer and check if it's correct.
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 2 steps

Blurred answer
Knowledge Booster
Stereochemistry in Organic Reactions
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY