The reaction SO2(g)+2H2S(g)⇌3S(s)+2H2O(g)SO2(g)+2H2S(g)⇌3S(s)+2H2O(g) is the basis of a suggested method for removal of SO2SO2, a pollutant that irritates airways causing coughing, from power-plant stack gases. The values below may be helpful when answering questions about the process. Substance ΔG∘fΔGf∘ (kJ/mol)(kJ/mol) ΔH∘fΔHf∘ (kJ/mol)(kJ/mol) H2O(g)H2O(g) −−228.6 −−241.8 H2O(l)H2O(l) −−237.1 −−285.8 SO2(g)SO2(g) −−300.4 −−296.9 SO3(g)SO3(g) −−370.4 −−395.2 H2S(g)H2S(g) −−33.01 −−20.17 S(s)S(s) 0 0 Assume that the partial pressure of sulfur dioxide, PSO2PSO2, is equal to the partial pressure of dihydrogen sulfide, PH2SPH2S, and therefore PSO2=PH2SPSO2=PH2S. If the vapor pressure of water is 24 torrtorr , calculate the equilibrium partial pressure of SO2SO2 (PSO2PSO2) in the system at 298 KK. Express the pressure in atmospheres to two significant figures. Kp= 8*10^15
The reaction SO2(g)+2H2S(g)⇌3S(s)+2H2O(g)SO2(g)+2H2S(g)⇌3S(s)+2H2O(g) is the basis of a suggested method for removal of SO2SO2, a pollutant that irritates airways causing coughing, from power-plant stack gases. The values below may be helpful when answering questions about the process. Substance ΔG∘fΔGf∘ (kJ/mol)(kJ/mol) ΔH∘fΔHf∘ (kJ/mol)(kJ/mol) H2O(g)H2O(g) −−228.6 −−241.8 H2O(l)H2O(l) −−237.1 −−285.8 SO2(g)SO2(g) −−300.4 −−296.9 SO3(g)SO3(g) −−370.4 −−395.2 H2S(g)H2S(g) −−33.01 −−20.17 S(s)S(s) 0 0 Assume that the partial pressure of sulfur dioxide, PSO2PSO2, is equal to the partial pressure of dihydrogen sulfide, PH2SPH2S, and therefore PSO2=PH2SPSO2=PH2S. If the vapor pressure of water is 24 torrtorr , calculate the equilibrium partial pressure of SO2SO2 (PSO2PSO2) in the system at 298 KK. Express the pressure in atmospheres to two significant figures. Kp= 8*10^15
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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The reaction
SO2(g)+2H2S(g)⇌3S(s)+2H2O(g)SO2(g)+2H2S(g)⇌3S(s)+2H2O(g)
is the basis of a suggested method for removal of SO2SO2, a pollutant that irritates airways causing coughing, from power-plant stack gases.
The values below may be helpful when answering questions about the process.
Substance | ΔG∘fΔGf∘ (kJ/mol)(kJ/mol) |
ΔH∘fΔHf∘ (kJ/mol)(kJ/mol) |
H2O(g)H2O(g) | −−228.6 | −−241.8 |
H2O(l)H2O(l) | −−237.1 | −−285.8 |
SO2(g)SO2(g) | −−300.4 | −−296.9 |
SO3(g)SO3(g) | −−370.4 | −−395.2 |
H2S(g)H2S(g) | −−33.01 | −−20.17 |
S(s)S(s) | 0 | 0 |
Assume that the partial pressure of sulfur dioxide, PSO2PSO2, is equal to the partial pressure of dihydrogen sulfide, PH2SPH2S, and therefore PSO2=PH2SPSO2=PH2S. If the vapor pressure of water is 24 torrtorr , calculate the equilibrium partial pressure of SO2SO2 (PSO2PSO2) in the system at 298 KK.
Express the pressure in atmospheres to two significant figures.
Kp= 8*10^15
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