The reaction PCl3(g) + Cl2(g) ⇌ PCl5(g) has Kp =0.0870 at 300 °C. A flask is charged with 0.50 atmPCl3, 0.50 atm Cl2, and 0.20 atm PCl5 at this temperature.(a) Use the reaction quotient to determine the directionthe reaction must proceed to reach equilibrium. (b) Calculatethe equilibrium partial pressures of the gases. (c) Whateffect will increasing the volume of the system have on themole fraction of Cl2 in the equilibrium mixture? (d) Thereaction is exothermic. What effect will increasing the temperatureof the system have on the mole fraction of Cl2 inthe equilibrium mixture?

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The reaction PCl3(g) + Cl2(g) ⇌ PCl5(g) has Kp =
0.0870 at 300 °C. A flask is charged with 0.50 atm
PCl3, 0.50 atm Cl2, and 0.20 atm PCl5 at this temperature.
(a) Use the reaction quotient to determine the direction
the reaction must proceed to reach equilibrium. (b) Calculate
the equilibrium partial pressures of the gases. (c) What
effect will increasing the volume of the system have on the
mole fraction of Cl2 in the equilibrium mixture? (d) The
reaction is exothermic. What effect will increasing the temperature
of the system have on the mole fraction of Cl2 in
the equilibrium mixture?

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