The reaction CHCI,(g) + Cl2(g) → CCI,(g) + HClg) is believed to proceed by this mechanism: Cl(g) → 2Clg) Clg) + CHC,(g) → HCl(g) + CCl,(g) CCl,(g) + Clg) CCL(g) fast slow fast What rate equation is consistent with this mechanism? (A) Rate = k[Cl,] (B) Rate = k[Cl[CHCI,] (C) Rate = k[Cl,[CHCI,] %3D (D) Rate = k[Cl,][CHCI,]

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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What can be
concluded about the
values of AH and
AS from this graph?
+100-
+50
-50-
*-100
0 100 200 300 400 500
Temperature, K-→
(A) AH >0, AS > 0
(B) AH >0, AS <0
(C) AH <0, AS > 0
(D) AH <0, AS < 0
a6, kJmol- -
Transcribed Image Text:What can be concluded about the values of AH and AS from this graph? +100- +50 -50- *-100 0 100 200 300 400 500 Temperature, K-→ (A) AH >0, AS > 0 (B) AH >0, AS <0 (C) AH <0, AS > 0 (D) AH <0, AS < 0 a6, kJmol- -
The reaction
CHCI,(g) + Cl2(g) → CCl,(g) + HCl(g)
is believed to proceed by this mechanism:
Cl(g) → 2Clg)
Clg) + CHC1,(g) → HCl(g) + CCl,(g)
CCl,(g) + Cl(g) → CCl,(g)
fast
slow
fast
What rate equation is consistent with this mechanism?
(A) Rate = k[Cl,]
(B) Rate = k[Cl[CHCI,]
(C) Rate = k[Cl,[CHCI,]
%3D
(D) Rate = k[Cl,][CHCI,]
Transcribed Image Text:The reaction CHCI,(g) + Cl2(g) → CCl,(g) + HCl(g) is believed to proceed by this mechanism: Cl(g) → 2Clg) Clg) + CHC1,(g) → HCl(g) + CCl,(g) CCl,(g) + Cl(g) → CCl,(g) fast slow fast What rate equation is consistent with this mechanism? (A) Rate = k[Cl,] (B) Rate = k[Cl[CHCI,] (C) Rate = k[Cl,[CHCI,] %3D (D) Rate = k[Cl,][CHCI,]
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