The quantity of antimony in a sample can be determined by an oxidation-reduction titration with an oxidizing agent. A 5.95 g sample of stibnite, an ore of antimony, is dissolved in hot, concentrated HCl(aq) and passed over a reducing agent so that all the antimony is in the form Sb³+(aq). The Sb³+(aq) is completely oxidized by 25.0 mL of a 0.135 M aqueous solution of KBr0,(aq). The unbalanced equation for the reaction is BrOz (aq) + Sb³+(aq) – Br (aq) + Sb³+(aq) (unbalanced) Calculate the amount of antimony in the sample and its percentage in the ore.

Chemistry: The Molecular Science
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Chapter17: Electrochemistry And Its Applications
Section: Chapter Questions
Problem 33QRT: Consider these half-reactions: (a) Which is the weakest oxidizing agent? (b) Which is the strongest...
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The quantity of antimony in a sample can be determined by an oxidation-reduction titration with an oxidizing agent. A
5.95 g sample of stibnite, an ore of antimony, is dissolved in hot, concentrated HCl(aq) and passed over a reducing agent
3+
so that all the antimony is in the form Sb³*(aq). The Sb³*(aq) is completely oxidized by 25.0 mL of a 0.135 M aqueous
solution of KBrO,(aq). The unbalanced equation for the reaction is
BrO (aq) + Sb3+
(aq)
Br (aq) + Sb+(aq) (unbalanced)
Calculate the amount of antimony in the sample and its percentage in the ore.
mass of antimony:
g
percentage of antimony:
%
Transcribed Image Text:The quantity of antimony in a sample can be determined by an oxidation-reduction titration with an oxidizing agent. A 5.95 g sample of stibnite, an ore of antimony, is dissolved in hot, concentrated HCl(aq) and passed over a reducing agent 3+ so that all the antimony is in the form Sb³*(aq). The Sb³*(aq) is completely oxidized by 25.0 mL of a 0.135 M aqueous solution of KBrO,(aq). The unbalanced equation for the reaction is BrO (aq) + Sb3+ (aq) Br (aq) + Sb+(aq) (unbalanced) Calculate the amount of antimony in the sample and its percentage in the ore. mass of antimony: g percentage of antimony: %
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