Homework Help is Here – Start Your Trial Now!
Science
Chemistry
The procedure of methylation of amines and thermal decomposition of quaternary ammonium hydroxides was first reported by Hofmann in 1851, but its value as a means of structure determination was not appreciated until 1881, when he published a report of its use to determine the structure of piperidine. Following are the results obtained by Hofmann. 1. CHI (excess), К,СО, 2. Ag,O, H,O 3. heat 4. CH3I (excess), K,CO3 5. Ag.O, H,О 6. heat C5H1|N C;H15N CH2=CHCH,CH=CH2 Piperidine (A) 1,4-Pentadiene

The procedure of methylation of amines and thermal decomposition of quaternary ammonium hydroxides was first reported by Hofmann in 1851, but its value as a means of structure determination was not appreciated until 1881, when he published a report of its use to determine the structure of piperidine. Following are the results obtained by Hofmann. 1. CHI (excess), К,СО, 2. Ag,O, H,O 3. heat 4. CH3I (excess), K,CO3 5. Ag.O, H,О 6. heat C5H1|N C;H15N CH2=CHCH,CH=CH2 Piperidine (A) 1,4-Pentadiene

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
See similar textbooks
icon
Related questions
Question

Show that these results are consistent with the structure of piperidine

The procedure of methylation of amines and thermal decomposition of quaternary ammonium hydroxides was first reported by Hofmann in 1851, but its value as a means of structure determination was not appreciated until 1881, when he published a report of its use to determine the structure of piperidine. Following are the results obtained by Hofmann. 1. CHI (excess), К,СО, 2. Ag,O, H,O 3. heat 4. CH3I (excess), K,CO3 5. Ag.O, H,О 6. heat C5H1|N C;H15N CH2=CHCH,CH=CH2 Piperidine (A) 1,4-Pentadiene
Transcribed Image Text:The procedure of methylation of amines and thermal decomposition of quaternary ammonium hydroxides was first reported by Hofmann in 1851, but its value as a means of structure determination was not appreciated until 1881, when he published a report of its use to determine the structure of piperidine. Following are the results obtained by Hofmann. 1. CHI (excess), К,СО, 2. Ag,O, H,O 3. heat 4. CH3I (excess), K,CO3 5. Ag.O, H,О 6. heat C5H1|N C;H15N CH2=CHCH,CH=CH2 Piperidine (A) 1,4-Pentadiene
Expert Solution
steps

Step by step

Solved in 3 steps with 7 images

SEE SOLUTIONCheck out a sample Q&A here
Blurred answer
Knowledge Booster
Protection of Groups in Organic Synthesis
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY
SEE MORE TEXTBOOKS