The observed spin-orbit splittings of the 'P3, and P, levels for Li, Na, K, Rb and Q3. Cs atoms are 0.3, 17.2, 57.7, 237.6 and 554.1 cm", respectively. Determine how this spin-orbit splitting depends on Z. Briefly explain such a Z dependence.

Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter15: Introduction To Electronic Spectroscopy And Structure
Section: Chapter Questions
Problem 15.56E
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Q3.
Cs atoms are 0.3, 17.2, 57.7, 237.6 and 554.1 cm", respectively. Determine how this spin-orbit
splitting depends on Z. Briefly explain such a Z dependence.
The observed spin-orbit splittings of the "P3, and 'P, levels for Li, Na, K, Rb and
Transcribed Image Text:Q3. Cs atoms are 0.3, 17.2, 57.7, 237.6 and 554.1 cm", respectively. Determine how this spin-orbit splitting depends on Z. Briefly explain such a Z dependence. The observed spin-orbit splittings of the "P3, and 'P, levels for Li, Na, K, Rb and
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