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The molecule CIF, belongs to the C4, point group. Use the character table below to answer the following questions. Cav A₁ کے ش E 2C C₂ 20 20d 1 1 1 1 1 Z A₂ 1 1 1 -1 -1 B₁ 1 -1 1 1 -1 B₂ 1 -1 1 -1 1 E 2 0 -2 0 0 (x, y) a) Draw CIF5 using a conventional cartesian coordinate system with the correct symmetry. (The Cl atom is in the center and is bonded to each of the 5 fluorine atoms.) b) Draw pictures showing how the p orbitals (x, y, and z) on Cl will transform under each operation of the group. c) Draw pictures showing how a i) dxy and a ii) dzz orbital on Cl would transform under each operation of the group. What are their Mulliken symbols? d) What are the irreducible representations for the SALCS of the 5 fluorine 2s orbitals? You do not need to draw a diagram or order the orbitals by energy, but for each molecular orbital symmetry, list all atomic orbitals and SALCs with that symmetry. Example: If this question were asking about the composition of the MOs of water (C₂, point group), your answer would include the following: a₁: 2s (oxygen), H₂ SALC, and 2pz (oxygen) e) Which molecular orbital do you predict to be the most bonding? Draw a picture of this orbital including the phase. f) d-orbitals are not important for the bonding description of CIF5. Give a brief reason why.

The molecule CIF, belongs to the C4, point group. Use the character table below to answer the following questions. Cav A₁ کے ش E 2C C₂ 20 20d 1 1 1 1 1 Z A₂ 1 1 1 -1 -1 B₁ 1 -1 1 1 -1 B₂ 1 -1 1 -1 1 E 2 0 -2 0 0 (x, y) a) Draw CIF5 using a conventional cartesian coordinate system with the correct symmetry. (The Cl atom is in the center and is bonded to each of the 5 fluorine atoms.) b) Draw pictures showing how the p orbitals (x, y, and z) on Cl will transform under each operation of the group. c) Draw pictures showing how a i) dxy and a ii) dzz orbital on Cl would transform under each operation of the group. What are their Mulliken symbols? d) What are the irreducible representations for the SALCS of the 5 fluorine 2s orbitals? You do not need to draw a diagram or order the orbitals by energy, but for each molecular orbital symmetry, list all atomic orbitals and SALCs with that symmetry. Example: If this question were asking about the composition of the MOs of water (C₂, point group), your answer would include the following: a₁: 2s (oxygen), H₂ SALC, and 2pz (oxygen) e) Which molecular orbital do you predict to be the most bonding? Draw a picture of this orbital including the phase. f) d-orbitals are not important for the bonding description of CIF5. Give a brief reason why.

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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The molecule CIF, belongs to the C4, point group. Use the character table below to answer the following questions. Cav A₁ کے ش E 2C C₂ 20 20d 1 1 1 1 1 Z A₂ 1 1 1 -1 -1 B₁ 1 -1 1 1 -1 B₂ 1 -1 1 -1 1 E 2 0 -2 0 0 (x, y) a) Draw CIF5 using a conventional cartesian coordinate system with the correct symmetry. (The Cl atom is in the center and is bonded to each of the 5 fluorine atoms.) b) Draw pictures showing how the p orbitals (x, y, and z) on Cl will transform under each operation of the group. c) Draw pictures showing how a i) dxy and a ii) dzz orbital on Cl would transform under each operation of the group. What are their Mulliken symbols? d) What are the irreducible representations for the SALCS of the 5 fluorine 2s orbitals? You do not need to draw a diagram or order the orbitals by energy, but for each molecular orbital symmetry, list all atomic orbitals and SALCs with that symmetry. Example: If this question were asking about the composition of the MOs of water (C₂, point group), your answer would include the following: a₁: 2s (oxygen), H₂ SALC, and 2pz (oxygen) e) Which molecular orbital do you predict to be the most bonding? Draw a picture of this orbital including the phase. f) d-orbitals are not important for the bonding description of CIF5. Give a brief reason why.
Transcribed Image Text:The molecule CIF, belongs to the C4, point group. Use the character table below to answer the following questions. Cav A₁ کے ش E 2C C₂ 20 20d 1 1 1 1 1 Z A₂ 1 1 1 -1 -1 B₁ 1 -1 1 1 -1 B₂ 1 -1 1 -1 1 E 2 0 -2 0 0 (x, y) a) Draw CIF5 using a conventional cartesian coordinate system with the correct symmetry. (The Cl atom is in the center and is bonded to each of the 5 fluorine atoms.) b) Draw pictures showing how the p orbitals (x, y, and z) on Cl will transform under each operation of the group. c) Draw pictures showing how a i) dxy and a ii) dzz orbital on Cl would transform under each operation of the group. What are their Mulliken symbols? d) What are the irreducible representations for the SALCS of the 5 fluorine 2s orbitals? You do not need to draw a diagram or order the orbitals by energy, but for each molecular orbital symmetry, list all atomic orbitals and SALCs with that symmetry. Example: If this question were asking about the composition of the MOs of water (C₂, point group), your answer would include the following: a₁: 2s (oxygen), H₂ SALC, and 2pz (oxygen) e) Which molecular orbital do you predict to be the most bonding? Draw a picture of this orbital including the phase. f) d-orbitals are not important for the bonding description of CIF5. Give a brief reason why.
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