The molar volume (cm³ mol*) of a binary liquid mixture at T and P is given by: V = 120x, + 70x2 + (15x1 + 8x2)x1X2 a) Find expressions for the partial molar volumes of species 1 and 2 at T and P. b) Show that when the derived expressions for the partial molar volumes are combined in accord with the summability relations, the given equation for V is recovered. c) Show that the derived expressions for the partial molar volumes satisfy the Gibbs/Duhem equation. d) Plot the values of V, V,, and V½ vs. X¡ in Excel. Label points V, V2, V,ºand Vº and show their values.
The molar volume (cm³ mol*) of a binary liquid mixture at T and P is given by: V = 120x, + 70x2 + (15x1 + 8x2)x1X2 a) Find expressions for the partial molar volumes of species 1 and 2 at T and P. b) Show that when the derived expressions for the partial molar volumes are combined in accord with the summability relations, the given equation for V is recovered. c) Show that the derived expressions for the partial molar volumes satisfy the Gibbs/Duhem equation. d) Plot the values of V, V,, and V½ vs. X¡ in Excel. Label points V, V2, V,ºand Vº and show their values.
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
Related questions
Question
ANSWER LETTER D ONLY PLEASE
Transcribed Image Text:The molar volume (cm³ mol*) of a binary liquid mixture at T and P is given by:
V = 120x1 + 70x2 + (15x1 + 8x2)x1X2
a) Find expressions for the partial molar volumes of species 1 and 2 at T and P.
b) Show that when the derived expressions for the partial molar volumes are combined in accord with the summability
relations, the given equation for V is recovered.
c) Show that the derived expressions for the partial molar volumes satisfy the Gibbs/Duhem equation.
d) Plot the values of V, V1, and V2 vs. Xı in Excel. Label points V1, V2, V°and V and show their values.
Expert Solution
This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
This is a popular solution!
Trending now
This is a popular solution!
Step by step
Solved in 3 steps with 1 images
Recommended textbooks for you
Introduction to Chemical Engineering Thermodynami…
Chemical Engineering
ISBN:
9781259696527
Author:
J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:
McGraw-Hill Education
Elementary Principles of Chemical Processes, Bind…
Chemical Engineering
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY
Elements of Chemical Reaction Engineering (5th Ed…
Chemical Engineering
ISBN:
9780133887518
Author:
H. Scott Fogler
Publisher:
Prentice Hall
Introduction to Chemical Engineering Thermodynami…
Chemical Engineering
ISBN:
9781259696527
Author:
J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:
McGraw-Hill Education
Elementary Principles of Chemical Processes, Bind…
Chemical Engineering
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY
Elements of Chemical Reaction Engineering (5th Ed…
Chemical Engineering
ISBN:
9780133887518
Author:
H. Scott Fogler
Publisher:
Prentice Hall
Industrial Plastics: Theory and Applications
Chemical Engineering
ISBN:
9781285061238
Author:
Lokensgard, Erik
Publisher:
Delmar Cengage Learning
Unit Operations of Chemical Engineering
Chemical Engineering
ISBN:
9780072848236
Author:
Warren McCabe, Julian C. Smith, Peter Harriott
Publisher:
McGraw-Hill Companies, The