The molar heat capacity of anhydrous potassium hexacyanoferrate (II) varies with temperature according the table below. Determine the change in enthalpy and entropy of bringing 314 g of K+[FeCN6] to 200 K from OK. Approximate the first 10 degrees using the Debye extrapolation (Cp = aT³). T(K) Cp (J/Kmol) T (K) Cp (J/Kmol) 10 20 30 40 50 60 70 80 90 100 2.09 14.43 36.44 62.55 87.03 111.0 131.4 149.4 165.3 179.6 110 120 130 140 150 160 170 180 190 200 192.8 204.0 215.2 226.4 237.6 247.3 256.5 265.1 273.0 280.3

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
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The molar heat capacity of anhydrous potassium hexacyanoferrate(II) varies
with temperature according the table below. Determine the change in enthalpy and entropy of
bringing 314 g of K4[FeCN6] to 200 K from OK. Approximate the first 10 degrees using the
Debye extrapolation (Cp = aT³).
T (K)
Cp
(J/Kmol)
T (K)
Cp
(J/Kmol)
30
40
50
60
70
80
90
100
10 20
2.09 14.43 36.44 62.55 87.03 111.0 131.4 149.4 165.3 179.6
110 120 130 140 150 160 170 180 190 200
192.8 204.0 215.2 226.4 237.6 247.3
256.5 265.1 273.0 280.3
Transcribed Image Text:The molar heat capacity of anhydrous potassium hexacyanoferrate(II) varies with temperature according the table below. Determine the change in enthalpy and entropy of bringing 314 g of K4[FeCN6] to 200 K from OK. Approximate the first 10 degrees using the Debye extrapolation (Cp = aT³). T (K) Cp (J/Kmol) T (K) Cp (J/Kmol) 30 40 50 60 70 80 90 100 10 20 2.09 14.43 36.44 62.55 87.03 111.0 131.4 149.4 165.3 179.6 110 120 130 140 150 160 170 180 190 200 192.8 204.0 215.2 226.4 237.6 247.3 256.5 265.1 273.0 280.3
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