/The melting point of benzene is 5.5°C. Predict the signs of AH, AS, and AG for melting of benzene at: (a) -5°C (b) 25°C

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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How do you solve 17.84? 

a négative enthalpy change
(b) a positive enthalpy change
AG=04-TAS
%3D
a positive entropy change
(d) a positive free-energy change
(e) a negative free-energy change
17.83 Which of the following reactions will be spontaneous at any
temperature?
(a) AH = +, AS
(b) ΔΗ =-, ΔS -
(d) AH = -,AS = +
%D
(c) AH = +, AS = +
(d) ΔΗ
17.84/The melting point of benzene is 5.5°C. Predict the signs of
AH, AS, and AG for melting of benzene at:
(b) 25°C
17.85 Consider a twofold expansion of 1 mol of an ideal gas at 25°C in
(a) -5°C
the isolated system shown in Figure 17.1.
(a) What are the values of AH, AS, and AG for the process?
(b) How does this process illustrate the second law of
thermodynamics?
17.86 Given the data in Problem 17.78, calculate AG for the vaporiza-
tion of benzene at:
(a) 70°C
(b) 80°C
(c) 90°C
|
Transcribed Image Text:a négative enthalpy change (b) a positive enthalpy change AG=04-TAS %3D a positive entropy change (d) a positive free-energy change (e) a negative free-energy change 17.83 Which of the following reactions will be spontaneous at any temperature? (a) AH = +, AS (b) ΔΗ =-, ΔS - (d) AH = -,AS = + %D (c) AH = +, AS = + (d) ΔΗ 17.84/The melting point of benzene is 5.5°C. Predict the signs of AH, AS, and AG for melting of benzene at: (b) 25°C 17.85 Consider a twofold expansion of 1 mol of an ideal gas at 25°C in (a) -5°C the isolated system shown in Figure 17.1. (a) What are the values of AH, AS, and AG for the process? (b) How does this process illustrate the second law of thermodynamics? 17.86 Given the data in Problem 17.78, calculate AG for the vaporiza- tion of benzene at: (a) 70°C (b) 80°C (c) 90°C |
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