The mechanism proposed for the oxidation of iodide ion, I, by the hypochlorite ion, CIO, in aqueous solution is shown. 1. ClO (aq) + H₂O(1) HCIO(aq) + OH¯(aq) fast in both directions 2. I-(aq) + HCIO(aq) HIO(aq) + Cl(aq) slow 3. HIO(aq) + OH- (aq) IO (aq) + H₂O(1) fast Complete the rate law for the formation of IO implied by this mechanism. →
The mechanism proposed for the oxidation of iodide ion, I, by the hypochlorite ion, CIO, in aqueous solution is shown. 1. ClO (aq) + H₂O(1) HCIO(aq) + OH¯(aq) fast in both directions 2. I-(aq) + HCIO(aq) HIO(aq) + Cl(aq) slow 3. HIO(aq) + OH- (aq) IO (aq) + H₂O(1) fast Complete the rate law for the formation of IO implied by this mechanism. →
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![The mechanism proposed for the oxidation of iodide ion, I, by the hypochlorite ion, ClO¯, in aqueous solution is shown.
fast in both directions
1. ClO (aq) + H,O(1) = HClO(aq) + OH (aq)
2. I (aq) + HClO(aq) → HIO(aq) + Cl-(aq)
slow
3. HIO(aq) + OH(aq) → IO¯(aq) + H₂O(1)
fast
Complete the rate law for the formation of IO implied by this mechanism.
ratek-
[10]
[CIO]
[CI]
[I]
[H₂O]
Answer Bank
[OH-]
[HIO]
[HCIO]](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F4e874eca-d11e-4d5d-96bf-b45c501c361b%2Fcf3fee41-e243-4e4d-81d0-188dcf096522%2Fkzypxt_processed.png&w=3840&q=75)
Transcribed Image Text:The mechanism proposed for the oxidation of iodide ion, I, by the hypochlorite ion, ClO¯, in aqueous solution is shown.
fast in both directions
1. ClO (aq) + H,O(1) = HClO(aq) + OH (aq)
2. I (aq) + HClO(aq) → HIO(aq) + Cl-(aq)
slow
3. HIO(aq) + OH(aq) → IO¯(aq) + H₂O(1)
fast
Complete the rate law for the formation of IO implied by this mechanism.
ratek-
[10]
[CIO]
[CI]
[I]
[H₂O]
Answer Bank
[OH-]
[HIO]
[HCIO]
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